Photometric determination of aqueous cobalt (II), nickel (II), copper (II) and iron (III) with 1-nitroso-2-naphthol-3,6-disulfonic acid disodium salt in gelatin films

• Authors: Elena Reshetnyak , Nataliia Ivchenko , Nataliya Nikitina
• Languages of publication: EN

Abstracts

EN

Photometric determination of aqueous Co(II), Cu(II), Ni(II) and Fe(III) was performed using indicator films prepared by immobilization of 1-nitroso-2-naphthol-3,6-disulfonic acid disodium salt (NRS) into hardened photographic film. Immobilization was based on electrostatic interaction of reagent and metal complexes with the gelatin. The isoelectric point pH of hardened gelatin (4.46±0.04) was evaluated by viscometry. Co(II), Fe(III), Ni(II) form 1:3 complexes with NRS in gelatin at pH 2 and Cu(II) forms 1:2 complexes. Their log β′ values were: Co-6.7, Fe-8.6, Cu-8.0, and Ni-6.4. The absorption maxima were: 370nm for NRS, and 430nm, 470nm, 495nm and 720nm for complexes of Co(II), Ni(II), Cu(II) and Fe(III). An algorithm for their simultaneous determination using the indicator films was developed. The detection limits were: clim(Co2+) = 0.45×10−5 M, clim(Fe3+) = 0.50×10−5 M, clim(Cu2+) = 0.67×10−5 M, clim(Ni2+) = 0.75×10−5 M,; and their sum clim(ΣMn+) = 0.82×10−5 M. [...]

Keywords

EN

Nitroso-R-salt; Gelatin film; Immobilization; Metal ions; Complex

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 5
• Pages: 1617-1623

Dates

published

1 - 10 - 2012

online

21 - 7 - 2012

Contributors

author

Elena Reshetnyak

• Department of Chemical Metrology, Chemical Faculty, Kharkiv V.N. Karazin National University, Kharkiv, 61022, Ukraine

author

Nataliia Ivchenko

• Department of Chemical Metrology, Chemical Faculty, Kharkiv V.N. Karazin National University, Kharkiv, 61022, Ukraine

author

Nataliya Nikitina

• Department of Chemical Metrology, Chemical Faculty, Kharkiv V.N. Karazin National University, Kharkiv, 61022, Ukraine

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Identifiers

DOI

10.2478/s11532-012-0081-7