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2012 | 10 | 5 | 1617-1623
Article title

Photometric determination of aqueous cobalt (II), nickel (II), copper (II) and iron (III) with 1-nitroso-2-naphthol-3,6-disulfonic acid disodium salt in gelatin films

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Abstracts
EN
Photometric determination of aqueous Co(II), Cu(II), Ni(II) and Fe(III) was performed using indicator films prepared by immobilization of 1-nitroso-2-naphthol-3,6-disulfonic acid disodium salt (NRS) into hardened photographic film. Immobilization was based on electrostatic interaction of reagent and metal complexes with the gelatin. The isoelectric point pH of hardened gelatin (4.46±0.04) was evaluated by viscometry. Co(II), Fe(III), Ni(II) form 1:3 complexes with NRS in gelatin at pH 2 and Cu(II) forms 1:2 complexes. Their log β′ values were: Co-6.7, Fe-8.6, Cu-8.0, and Ni-6.4. The absorption maxima were: 370nm for NRS, and 430nm, 470nm, 495nm and 720nm for complexes of Co(II), Ni(II), Cu(II) and Fe(III). An algorithm for their simultaneous determination using the indicator films was developed. The detection limits were: clim(Co2+) = 0.45×10−5 M, clim(Fe3+) = 0.50×10−5 M, clim(Cu2+) = 0.67×10−5 M, clim(Ni2+) = 0.75×10−5 M,; and their sum clim(ΣMn+) = 0.82×10−5 M. [...]
Publisher

Journal
Year
Volume
10
Issue
5
Pages
1617-1623
Physical description
Dates
published
1 - 10 - 2012
online
21 - 7 - 2012
Contributors
  • Department of Chemical Metrology, Chemical Faculty, Kharkiv V.N. Karazin National University, Kharkiv, 61022, Ukraine
  • Department of Chemical Metrology, Chemical Faculty, Kharkiv V.N. Karazin National University, Kharkiv, 61022, Ukraine
  • Department of Chemical Metrology, Chemical Faculty, Kharkiv V.N. Karazin National University, Kharkiv, 61022, Ukraine, nikitina@univer.kharkov.ua
References
  • [1] S.B. Savvin, S.N. Shtykov, A.V. Mikhailova, Russ. Chem. Rev. 75, 341 (2006) http://dx.doi.org/10.1070/RC2006v075n04ABEH001189[Crossref]
  • [2] T.G. Dzherayan, V.M. Shkinev, L.K. Shpigun, P.M. Kamilova, K.E. Geckler, Talanta 57, 7 (2002) http://dx.doi.org/10.1016/S0039-9140(01)00675-0[Crossref]
  • [3] K. Nakashima, J. Duhamel, M.A. Winnik, J. Phys. Chem. 97, 10702 (1993) http://dx.doi.org/10.1021/j100143a029[Crossref]
  • [4] M. Bacci, F. Baldini, A.M. Scheggi, Anal. Chim. Acta. 207, 343 (1988) http://dx.doi.org/10.1016/S0003-2670(00)80812-0[Crossref]
  • [5] R. Narayanaswamy, F. Sevilla III Anal. Chim. Acta. 189, 365 (1986) http://dx.doi.org/10.1016/S0003-2670(00)83739-3[Crossref]
  • [6] L. Vachoud, N. Zidowicz, A. Domard, Int. J. Biol. Macromol. 28, 93 (2001) http://dx.doi.org/10.1016/S0141-8130(00)00151-3[Crossref]
  • [7] N.A. D’yachenko, A.K. Trofimchuk, V.V. Sukhan, J. Anal. Chem. 57, 1022 (2008) http://dx.doi.org/10.1023/A:1020977407784[Crossref]
  • [8] N.A. Nikitina, E.A. Reshetnyak, N.V. Svetlova, N.O. Mchedlov-Petrossyan, J. Braz. Chem. Soc. 22, 855 (2011). http://dx.doi.org/10.1590/S0103-50532011000500007[Crossref]
  • [9] M. Saleem, P. Tahira, R. Qadeer, Colloids and Surfaces A: Physicochem. Eng. Aspects 292, 246 (2007) http://dx.doi.org/10.1016/j.colsurfa.2006.06.035[Crossref]
  • [10] N.A. Gavrilenko, O.V. Mokhova, J. Anal. Chem. 63, 1038 (2008) http://dx.doi.org/10.1134/S106193480811004X[Crossref]
  • [11] S. Rastegarzadeh, V. Rezaei, J. Anal. Chem. 63, 897 (2008) http://dx.doi.org/10.1134/S1061934808090189[Crossref]
  • [12] M.M.F. Choi, J. Photochem. and Photobiol. A: Chemistry 114, 235 (1998) http://dx.doi.org/10.1016/S1010-6030(98)00220-2[Crossref]
  • [13] L.P. Loginova, O.Yu. Konovalova, Talanta 77, 915 (2008) http://dx.doi.org/10.1016/j.talanta.2008.07.051[Crossref]
  • [14] V.V. Kuznetsov, S.V. Sheremet’ev, J. Anal. Chem. 64, 886 (2009) http://dx.doi.org/10.1134/S1061934809090032[Crossref]
  • [15] O.V. Mikhailov, Zhelatin-immobilizovanye metallokompleksy (Nauchny Mir, Moskva, 2004) (in Russian)
  • [16] T. Geethakrishman, P.K. Palanisamy, Current Science 89, 1894 (2005)
  • [17] E.A. Reshetnyak, N.A. Nikitina, L.P. Loginova, N.O. Mchedlov-Petrossyan, N.V. Svetlova, Kharkov University Bulletin. Chemical Series 13, 67 (2005)
  • [18] E.A. Reshetnyak, V.E. Asmolov, N.N. Nemets, N.A. Nikitina, Kharkov University Bulletin. Chemical Series 18, 74 (2010)
  • [19] S.V. Sheremet’ev, V.V. Kuznetsov, J. Anal. Chem. 62, 319 (2007) http://dx.doi.org/10.1134/S1061934807040041[Crossref]
  • [20] A.E. Martell, R.M. Smith, Critical Stability Constants. Volume 3: Other Organic Ligands (Plenum Press, New York, London, 1977)
  • [21] W.H. Shipmen, S.C. Foti, Wilbur Simon, Anal. Chem. 27, 1240 (1955) http://dx.doi.org/10.1021/ac60104a010[Crossref]
  • [22] T. Nakashima, K. Yoshimura, H. Waki, Talanta 37, 735 (1990) http://dx.doi.org/10.1016/0039-9140(90)80103-M[Crossref]
  • [23] S. Banerjee, R.K. Dutta, Z. Anal. Chem. 277, 379 (1975) http://dx.doi.org/10.1007/BF00423789[Crossref]
  • [24] V.N. Losev, S.L. Didukh, A.K. Trofimchuk, V.N. Leshchenko, Mendeleev Commun. 19, 167(2009) http://dx.doi.org/10.1016/j.mencom.2009.05.020[Crossref]
  • [25] J.Z. Lu, S. J. Zhang, Microchem. J. 52, 315 (1995) http://dx.doi.org/10.1006/mchj.1995.1102[Crossref]
  • [26] M.A. Taher, Anal. Chim. Acta 408, 153 (2000) http://dx.doi.org/10.1016/S0003-2670(99)00796-5[Crossref]
  • [27] B.K. Puri, S. Balani, Talanta. 42, 337 (1995) http://dx.doi.org/10.1016/0039-9140(95)01399-V[Crossref]
  • [28] J. Ghasemi, N. Shahabadi, H.R. Seraji, Anal. Chim. Acta 510, 121 (2004) http://dx.doi.org/10.1016/j.aca.2003.12.053[Crossref]
  • [29] F. Umland, A. Yanssen, D. Thierig, G. Wünsch, Theorle und Praktische Anwendung von Komplexbildnern (Akademische Verlagsgesellschaft, Frankfurt, 1971) (Translated under the title Kompleksnye soedineniya v analiticheskoi khimii (Mir, Moscow, 1975)) (in Russian)
  • [30] T.H. James, Theory of the Photographic Process, 4th edition (Macmillan, New York, 1977)
  • [31] M. Beck, I. Nagipal. Chemistry of Complex Equilibria (Budapest Akademiai Kiado, Budapest, 1989)
  • [32] V.M. Ivanov, C.T.T. Mai, V.N. Figurovskaya, A.M. Mamedova, N.I. Ershova, J. Anal. Chem. 61, 859 (2006) http://dx.doi.org/10.1134/S1061934806090048[Crossref]
  • [33] V.M. Ivanov, V.N. Figurovskaya, N.I. Ershova, A.M. Mamedova, C.T.T. Mai, J. Anal. Chem. 62, 325 (2007) http://dx.doi.org/10.1134/S1061934807040053[Crossref]
  • [34] O. Zaporozhets, N. Petruniock, O. Bessarabova, V. Sukhan, Talanta 49, 899 (1999) http://dx.doi.org/10.1016/S0039-9140(99)00085-5[Crossref]
  • [35] O. Zaporozhets, O Gawer, V. Sukhan, Colloids and Surfaces A: Physicochem. Eng. Aspects 147, 273 (1999) http://dx.doi.org/10.1016/S0927-7757(98)00706-7[Crossref]
  • [36] L.A. Currie, Pure Appl. Chem. 67, 1699 (1995) http://dx.doi.org/10.1351/pac199567101699[Crossref]
  • [37] Predelno dopustimy kolichestva khimicheskih, videlyayuschiusya iz materialov, kontaktiruyuschih s pischevimi prodyktami. Gigienicheskie normative (Federalny Tsentr Gossanepidnadzora Minzdrava Rossii, Moskva, 2000) (in Russian)
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-012-0081-7
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