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Journal

2012 | 10 | 5 | 1647-1656

Article title

Conformational isomerism of 1-butene secondary ozonide as studied by means of matrix isolation infrared absorption spectroscopy

Content

Title variants

Languages of publication

EN

Abstracts

EN
Theoretical calculations of structures, stability and vibrational spectra of 1-butene secondary ozonide (SOZ) conformers were performed using DFT method B3LYP with a 6-311++G(3df, 3pd) basis set. The calculations predict six staggered structures of 1-butene SOZ. The FTIR spectra of 1-butene SOZ isolated in Ar, N2 and Xe matrices were recorded. It was found that nitrogen is the best suited for the matrix isolation of 1-butene SOZ. The bandwidth of the spectral bands of the ozonide isolated in nitrogen was as narrow as 2 cm−1. For the first time the existence of five conformers of 1-butene SOZ were confirmed experimentally by means of matrix isolation infrared absorption spectroscopy. The equatorial gauche (∠OCCC=−66.1°) conformer was proved theoretically and experimentally to be the most stable. It was found that due to high potential barriers of the conformational transitions annealing of the matrix is useless for the assignment of spectral bands to various conformers of 1-butene SOZ. Using the hot nozzle technique the van’t Hoff experimental plots were made for three additional conformers of 1-butene SOZ and experimental ΔH values for these additional conformers were established. The crystallization problems of 1-butene SOZ are discussed which accounts for the rich conformational diversity of the ozonide as well as high conformational barriers for axial-equatorial transitions. [...]

Publisher

Journal

Year

Volume

10

Issue

5

Pages

1647-1656

Physical description

Dates

published
1 - 10 - 2012
online
21 - 7 - 2012

Contributors

  • Institute of Physics, Center for Physical Sciences and Technology, LT-02300, Vilnius, Lithuania
  • Department of General Physics and Spectroscopy, Vilnius University, 2734, Vilnius, Lithuania
  • Department of General Physics and Spectroscopy, Vilnius University, 2734, Vilnius, Lithuania

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-012-0077-3
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