Sol-gel synthesis and study of neodymium substitution effects in Co-Al-Nd-O system with possible applications as novel inorganic pigments

• Authors: Dalia Jonynaite , Darius Jasaitis , Rimantas Raudonis , Algirdas Selskis , Remigijus Juskenas , Jurate Senvaitiene , Aivaras Kareiva
• Languages of publication: EN

Abstracts

EN

In the present work, the formation of cobalt aluminium spinel (CoAl2O4) as well as novel cobalt neodymium-aluminates with nominal compositions of CoAl1.75Nd0.25O4, CoAl1.5Nd0.5O4 and CoAlNdO4 by an aqueous sol-gel process and the sinterability of the products are investigated. The metal ions, generated by dissolving starting materials of metals in the diluted acetic acid were complexed by 1,2-ethanediol to obtain the precursors for the mixed metal ceramics. The phase purity of the synthesized compounds was characterized by powder X-ray diffraction analysis and infrared spectroscopy. The microstructural evolution and morphological features of the products were studied by scanning electron microscopy and atomic force microscopy, which together with the optical characterization of these new compounds showed that the sol-gel-derived materials could be successfully used as effective cobalt-based ceramic pigments. [...]

Keywords

EN

Sol-gel preparation; Cobalt aluminates; Neodymium substitution effect; Pigments; Glazes

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 5
• Pages: 1574-1583

Dates

published

1 - 10 - 2012

online

21 - 7 - 2012

Contributors

author

Dalia Jonynaite

• Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

author

Darius Jasaitis

• Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

author

Rimantas Raudonis

• Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

author

Algirdas Selskis

author

Remigijus Juskenas

author

Jurate Senvaitiene

• Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

author

Aivaras Kareiva

• Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

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Identifiers

DOI

10.2478/s11532-012-0072-8