Thermo-responsiveness of polysiloxanes grafted with poly(dimethyl acrylamide) segments

• Authors: Anca Rusu Hodorog , Constanta Ibanescu , Ioana Moleavin , Nicolae Hurduc
• Languages of publication: EN

Abstracts

EN

Thermo-sensitive polymers are of outstanding importance due to their ability to undergo controlled major changes in their properties as a response to minor modifications in temperature. The syntheses of novel polymers by grafting polysiloxane containing chlorobenzyl groups in the side chain by the homopolymerization of N,N′-dimethyl acrylamide (DMA) or the copolymerization of DMA and methyl methacrylate (MMA) using SET-LRP technique are presented. The polymers were characterized by 1H-NMR, UV, and fluorescence spectroscopy, and DSC. The thermo-sensitivity and the lower critical solution temperature (LCST), as well as the aggregation phenomena during the phase transition are evidenced by dynamic light scattering (DLS) and rheology. [...]

Keywords

EN

Thermo-sensitive polymers; Polysiloxane; Poly(N,N′-dimethyl acrylamide); Rheology; LCST

• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 4
• Pages: 1338-1348

Dates

published

1 - 8 - 2012

online

29 - 5 - 2012

Contributors

author

Anca Rusu Hodorog

• Department of Natural and Synthetic Polymers, «Gheorghe Asachi» Technical University of Iasi, 700050, Iasi, Romania

author

Constanta Ibanescu,

author

Ioana Moleavin

• LIST Saclay, Laboratoire Capteurs et Architectures Électroniques, CEA, F-91191, Gif-sur-Yvette Cedex, France

author

Nicolae Hurduc

• Department of Natural and Synthetic Polymers, «Gheorghe Asachi» Technical University of Iasi, 700050, Iasi, Romania,

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Identifiers

DOI

10.2478/s11532-012-0061-y