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Journal
2012 | 10 | 4 | 1338-1348
Article title

Thermo-responsiveness of polysiloxanes grafted with poly(dimethyl acrylamide) segments

Content
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Languages of publication
EN
Abstracts
EN
Thermo-sensitive polymers are of outstanding importance due to their ability to undergo controlled major changes in their properties as a response to minor modifications in temperature. The syntheses of novel polymers by grafting polysiloxane containing chlorobenzyl groups in the side chain by the homopolymerization of N,N′-dimethyl acrylamide (DMA) or the copolymerization of DMA and methyl methacrylate (MMA) using SET-LRP technique are presented. The polymers were characterized by 1H-NMR, UV, and fluorescence spectroscopy, and DSC. The thermo-sensitivity and the lower critical solution temperature (LCST), as well as the aggregation phenomena during the phase transition are evidenced by dynamic light scattering (DLS) and rheology. [...]
Publisher
Journal
Year
Volume
10
Issue
4
Pages
1338-1348
Physical description
Dates
published
1 - 8 - 2012
online
29 - 5 - 2012
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-012-0061-y
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