Supported H4SiW12O40 catalysts for α-pinene isomerization

• Authors: József-Zsolt Szücs-Balázs , Maria Coroş , Adrian Woiczechowski-Pop , Gabriela Blăniƫă , Mircea Vlassa
• Languages of publication: EN

Abstracts

EN

The heterogeneous isomerization of α-pinene was studied at 100, 130 and 160°C using 10% supported H4SiW12O40 (SiW) on SiO2, TiO2 and HZSM-5. The effect of the reaction temperature and the concentration of the catalyst over the conversion of α-pinene and the selectivity of camphene, limonene and terpinolene had been monitored. The recovery, reuse and leaching effect of the catalysts were studied. Simple, environmentally friendly and economic methods for the synthesis of camphene and limonene were developed and optimized. [...]

Keywords

EN

Heteropolyacids; Monoterpenes; Catalytic activity; Isomerization; Selectivity

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 4
• Pages: 1208-1217

Dates

published

1 - 8 - 2012

online

29 - 5 - 2012

Contributors

author

József-Zsolt Szücs-Balázs

• Institute of Chemistry Research Raluca Ripan, Babeş-Bolyai University, 400294, Cluj-Napoca, Romania

author

Maria Coroş

• Institute of Chemistry Research Raluca Ripan, Babeş-Bolyai University, 400294, Cluj-Napoca, Romania

author

Adrian Woiczechowski-Pop

• Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, 400028, Cluj-Napoca, Romania

author

Gabriela Blăniƫă

• National Institute of Research and Development of Isotopic and Molecular Technologies, 400293, Cluj-Napoca, Romania

author

Mircea Vlassa

• Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, 400028, Cluj-Napoca, Romania

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Identifiers

DOI

10.2478/s11532-012-0039-9