Spectroscopic and magnetic properties of Cu(II) complexes with selected biologically important ligands

• Authors: Renata Świsłocka , Monika Kalinowska , Wiesława Ferenc , Jan Sarzyński , Włodzimierz Lewandowski
• Languages of publication: EN

Abstracts

EN

The aim of this work was to study the spectroscopic and magnetic properties of copper(II) o-, m-, p-aminobenzoates, o-, m-, p-methoxybenzoates and o-, m- and p-nitrobenzoates. The complexes were synthesized and their compositions were evaluated by elementary analysis. The infrared and Raman spectra for Cu(II) aminobenzoates, methoxybenzoates and nitrobenzoates were recorded and assigned. The obtained data were compared with those previously published for aminobenzoic, methoxybenzoic and nitrobenzoic acids and their sodium salts. The structures of Cu(II) o-, m-, p-aminobenzoates, o-, m-, p-methoxybenzoates and o-, m- and p-nitrobenzoates as well as the change in the electronic charges distribution caused by Cu(II) complex formation were discussed.

Keywords

EN

Methoxybenzoate; Aminobenzoate; Nitrobenzoate; Spectroscopic study; Magnetic study

• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 4
• Pages: 1095-1105

Dates

published

1 - 8 - 2012

online

29 - 5 - 2012

Contributors

author

Renata Świsłocka

• Division of Chemistry, Bialystok University of Technology, 15-435, Białystok, Poland

author

Monika Kalinowska

• Division of Chemistry, Bialystok University of Technology, 15-435, Białystok, Poland

author

Wiesława Ferenc

• Department of General and Coordination Chemistry, Maria Curie-Sklodowska University, 20-031, Lublin, Poland

author

Jan Sarzyński

• Institute of Physics, Maria Curie-Sklodowska University, 20-031, Lublin, Poland

author

Włodzimierz Lewandowski

• Division of Chemistry, Bialystok University of Technology, 15-435, Białystok, Poland,

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Identifiers

DOI

10.2478/s11532-012-0026-1