Chiral enantiopure bis(thio)ureas derived from TADDOL and their carboxylate complexation capacity

• Authors: Dragos Gherase , Christian Roussel
• Languages of publication: EN

Abstracts

EN

New chiral enantiopure ureas and thioureas with (R,R)-TADDOL backbone were synthesized. Bis-(thio)ureas with C2 symmetry were obtained from TADDOL iso(thio)cyanates and bifunctional amino-(thio)ureas from TADDAMINE, respectively. These were tested for carboxylate recognition capacity and the association constant was determined for the most stable complex. [...]

Keywords

EN

TADDOL; Enantiopure (thio)urea; Carboxylate recognition

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 4
• Pages: 1066-1072

Dates

published

1 - 8 - 2012

online

29 - 5 - 2012

Contributors

author

Dragos Gherase

author

Christian Roussel

• UMR ISM2: Chirosciences, Université Paul Cézanne, Marseille, 13397 CEDEX 20, France

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Identifiers

DOI

10.2478/s11532-012-0011-8