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Abstracts
A simple and efficient protocol for the preparation of a series of N-alkyl-3-boronopyridinium salts is described which requires exposure of 3-pyridineboronic acid neopentylglycol ester and corresponding alkyle halide to microwave irradiation followed by boronic ester hydrolysis. The technique employed drastically reduces the reaction time and prevents thermal degradation and the formation of side products. Water solutions of the obtained boronopyridinium salts are shown to be stable at room temperature in wide pH range as well as in the presence of hydrogen peroxide at pH 10.0 for 72 h. [...]
Journal
Year
Volume
Issue
Pages
1059-1065
Physical description
Dates
published
1 - 8 - 2012
online
29 - 5 - 2012
Contributors
author
author
- Laboratory of IMRCP, UMR 5623 CNRS, Paul Sabatier University, Toulouse, 31062, France
author
- L.M.Litvinenko Institute of Physical Organic Chemistry & Coal Chemistry, 83114, Donetsk, Ukraine
author
author
- NMR Service, Paul Sabatier University, Toulouse, 31062, France
author
- Laboratory of IMRCP, UMR 5623 CNRS, Paul Sabatier University, Toulouse, 31062, France
author
- Laboratory of IMRCP, UMR 5623 CNRS, Paul Sabatier University, Toulouse, 31062, France
author
- Laboratory of IMRCP, UMR 5623 CNRS, Paul Sabatier University, Toulouse, 31062, France
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-012-0006-5