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Journal
2012 | 10 | 2 | 360-367
Article title

Synthesis of dibromo ketones by the reaction of the environmentally benign H2O2-HBr system with oximes

Content
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Languages of publication
EN
Abstracts
EN
It was found that oximes undergo deoximation in the presence of the H2O2aq-HBraq system to form ketones and bromo ketones. This reaction provided the basis for the synthesis of dibromo ketones in yields varying from 40% to 94%. This method is environmentally friendly, sustainable, and easy to perform. The results of this investigation extend the potential of the use of oximes for the protection of carbonyl group, thus offering the ability to perform not only conventional deoximation but also the subsequent bromination of ketones. The reaction is easily scaled up and dibromo ketones can be prepared in gram amounts. [...]
Publisher
Journal
Year
Volume
10
Issue
2
Pages
360-367
Physical description
Dates
published
1 - 4 - 2012
online
29 - 1 - 2012
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-011-0158-8
Identifiers
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