Physicochemical characteristics of 2-, 3- and 4-methylpyridinium tetrachloroferrates(III)

• Authors: Dariusz Wyrzykowski , Michał Wera , Artur Sikorski , Dagmara Jacewicz , Lech Chmurzyński
• Languages of publication: EN

Abstracts

EN

The crystal structure of 2-methylpyridinium tetrachloroferrate(III) was determined. The iron cation is tetracoordinated by chloride anions, and it adopts a slightly distorted tetrahedral coordination with three angles smaller, two almost equal and one larger than the tetrahedral. The compound is isostructural with its 3-, and 4-methylpyridinium analogues. The thermal properties of 2-, 3- and 4-methylpyridinium tetrachloroferrates(III) have been studied using TG and DSC techniques. The compounds exhibit a high stability in the melt. [...]

Keywords

EN

Tetrachloroferrate(III); Crystal structure; Thermal properties

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2011
• Volume: 9
• Issue: 6
• Pages: 1096-1101

Dates

published

1 - 12 - 2011

online

27 - 9 - 2011

Contributors

author

Dariusz Wyrzykowski

• Department of General and Inorganic Chemistry, Faculty of Chemistry, University of Gdańsk, 80 952, Gdańsk, Poland

author

Michał Wera

• Department of Physical Chemistry, Faculty of Chemistry, University of Gdańsk, 80 952, Gdańsk, Poland

author

Artur Sikorski

• Department of Physical Chemistry, Faculty of Chemistry, University of Gdańsk, 80 952, Gdańsk, Poland

author

Dagmara Jacewicz

• Department of General and Inorganic Chemistry, Faculty of Chemistry, University of Gdańsk, 80 952, Gdańsk, Poland

author

Lech Chmurzyński

• Department of General and Inorganic Chemistry, Faculty of Chemistry, University of Gdańsk, 80 952, Gdańsk, Poland

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Identifiers

DOI

10.2478/s11532-011-0106-7