A novel redox-active calix[4]arene-tetrathiafulvalene dyad

• Authors: Bang-Tun Zhao , Xiao-Min Zhu , Qi-Ming Peng , Zhen-Ning Yan , Franck Derf , Marc Sallé
• Languages of publication: EN

Abstracts

EN

A novel redox-active calix[4]arene-TTF 5 was prepared by the reaction of p-tert-butylcalix[4]arene 4 with the tosylated TTF 3 in the presence of cesium fluoride. The structure of the dyad 5 was identified by X-ray diffraction analysis, and the preliminary electrochemical properties of 5 were investigated by cyclic voltammetry (CV), for which two reversible one-electron waves were observed. Moreover, the UV-vis absorption spectra studies show that the dyad 5 undergoes progressive oxidation at the TTF moiety in presence of increasing amounts of Cu2+ or Hg2+. [...]

Keywords

EN

Calix[4]arene; Tetrathiafulvalene; Crystal structure; Cyclic voltammetry

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2011
• Volume: 9
• Issue: 6
• Pages: 1102-1108

Dates

published

1 - 12 - 2011

online

27 - 9 - 2011

Contributors

author

Bang-Tun Zhao

• Department of Chemistry, Luoyang Normal University, Luoyang, 471022, P. R. China

author

Xiao-Min Zhu

• Department of Chemistry, Zhengzhou University, Zhengzhou, 450001, P. R. China

author

Qi-Ming Peng

• Department of Chemistry, Zhengzhou University, Zhengzhou, 450001, P. R. China

author

Zhen-Ning Yan

• Department of Chemistry, Zhengzhou University, Zhengzhou, 450001, P. R. China

author

Franck Derf

• Laboratoire MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, F-49045, Angers, France

author

Marc Sallé

• Laboratoire MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, F-49045, Angers, France

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Identifiers

DOI

10.2478/s11532-011-0104-9