Ternary ion-association complexes between the indium(III) - 4-(2-pyridylazo)resorcinol anionic chelate and some tetrazolium cations

• Authors: Galya Toncheva , Kiril Gavazov , Vanya Lekova , Kirila Stojnova , Atanas Dimitrov
• Languages of publication: EN

Abstracts

EN

Complex formation and liquid-liquid extraction were studied in systems containing indium(III), 4-(2-pyridylazo)resorcinol (PAR), tetrazolium salt (TZS), water and chloroform. Two different TZS were used: 2,3,5-triphenyl-2H-tetrazolium chloride (TTC) and 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl-2H-tetrazolium bromide (MTT). The optimum conditions for extraction of In(III) as a ternary complex, (TT+)[In(PAR)2] or (MTT+)[In(PAR)2], were found: pH, extraction time, concentration of PAR and concentration of TZS. The constants of extraction (Kex), constants of association (β), constants of distribution (KD) and recovery factors (R%) were determined. The apparent molar absorptivities in chloroform were calculated to be ɛ′520=6.6×104 L mol−1 cm−1 and ɛ′515=7.1×104 L mol−1 cm−1 for the systems with TTC (I) and MTT (II), respectively. Beer’s law was obeyed for In(III) concentrations up to 3.4 µg mL−1 in both the cases. The limits of detection (LOD=0.07 µg mL−1I and LOD=0.12 µg mL−1II), limits of quantification (LOQ=0.24 µg mL−1I and LOQ=0.41 µg mL−1II) and Sandell’s sensitivities (SS) were estimated as well. [...]

Keywords

EN

Indium; Liquid-liquid extraction; Spectrophotometry; Triphenyltetrazolium; Thiazolyl Blue Tetrazolium

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2011
• Volume: 9
• Issue: 6
• Pages: 1143-1149

Dates

published

1 - 12 - 2011

online

27 - 9 - 2011

Contributors

author

Galya Toncheva

• Department of General and Inorganic Chemistry, University of Plovdiv, 4000, Plovdiv, Bulgaria

author

Kiril Gavazov

• Department of General and Inorganic Chemistry, University of Plovdiv, 4000, Plovdiv, Bulgaria

author

Vanya Lekova

• Department of General and Inorganic Chemistry, University of Plovdiv, 4000, Plovdiv, Bulgaria

author

Kirila Stojnova

• Department of General and Inorganic Chemistry, University of Plovdiv, 4000, Plovdiv, Bulgaria

author

Atanas Dimitrov

• Department of General and Inorganic Chemistry, University of Plovdiv, 4000, Plovdiv, Bulgaria

References

• [1] P.I. Fedorov, R.H. Akchurin, Indij (Nauka, MAIK Nauka/Interperiodika, Moskow, 2000) (in Russian)
• [2] J. Polendniok, Water, Air, Soil Pollut. 186, 343 (2007) http://dx.doi.org/10.1007/s11270-007-9491-0[Crossref]
• [3] S.A. Wood, I.M. Samson, Ore Geol. Rev. 28, 57 (2006) http://dx.doi.org/10.1016/j.oregeorev.2003.06.002[Crossref]
• [4] A.M. Alfantazi, R.R. Moskalyk, Miner. Eng. 16, 687 (2003) http://dx.doi.org/10.1016/S0892-6875(03)00168-7[Crossref]
• [5] J. Polendniok, F. Buhl, Chem. Anal. (Warsaw) 51, 631 (2006)
• [6] A. Reller, T. Bublies, T. Staudinger, I. Oswald, S. Meissner, M. Allen, GAIA 18, 127 (2009)
• [7] K. Vang, F. Liu, H. Ye, X. Zhang, Iran. J. Chem. Chem. Eng. 29, 19 (2010)
• [8] C. Mikolajczak, Technical papers, White papers (Indium Corporation, USA, 2011) http://www.indium.com/techlibrary/whitepapers/availability-of-indium-andgallium
• [9] A.P. Paiva, Sep. Sci. Technol. 36, 1395 (2001) http://dx.doi.org/10.1081/SS-100103878[Crossref]
• [10] J.S. Liu, H. Chen, X.Y. Chen, Z.L. Guo, Y.C. Hu, C.P. Liu, Y.Z. Sun, Hydrometallurgy 82,137 (2006) http://dx.doi.org/10.1016/j.hydromet.2006.03.008[Crossref]
• [11] J.-H. Yao, Y.-W. Li, Yejin Fenxi/Metallurgical Analysis 30, 45 (2010)
• [12] A.A. Huseyinli, R. Alieva, S. Haciyeva, T. Güray, J. Hazard. Mater. 163, 1001 (2009) http://dx.doi.org/10.1016/j.jhazmat.2008.07.055[Crossref]
• [13] P.P. Kish, S.T. Orlovsky, Zh. Anal. Khim. 17, 1057 (1962) (in Russian)
• [14] C.P. Vibhute, S.M. Khopkar, Analyst 111, 435 (1986) http://dx.doi.org/10.1039/an9861100435[Crossref]
• [15] L.L. Kolomiets, I.V. Pyatnitskii, Ukr. Khim. Zh. 45, 62 (1979) (in Russian)
• [16] E.A. Biryuk, R.V. Ravitskaya, Zh. Anal. Khim. 26, 735 (1971) (in Russian)
• [17] Z. Marczenko, M. Balcerzak, Metod’y spektrofotometrii v UF I vidimoj oblastyakh v neorganicheskom analize (Binom. Laboratoriya znanij, Moskow, 2007) (in Russian)
• [18] M. Hniličková, Collection Czech. Chem. Commun. 29, 1424 (1964)
• [19] Y.K. Agrawal, V.J. Bhatt, Analyst 111, 57 (1986) http://dx.doi.org/10.1039/an9861100057[Crossref]
• [20] A.I. Busev, V.M. Ivanov, N.S. Khlibova, Zh. Anal. Khim. 22, 547 (1967) (in Russian)
• [21] S.A. Abbasi, Anal. Lett. 21, 1705 (1988) http://dx.doi.org/10.1080/00032718808066522[Crossref]
• [22] N.K. Agnihotri, S. Ratnani, V.K. Singh, H.B. Singh, Anal. Sci. 19, 1297 (2003) http://dx.doi.org/10.2116/analsci.19.1297[Crossref]
• [23] V.K. Singh, N.K. Agnihotri, H.B. Singh, R.L. Sharma, Talanta 55, 799 (2001) http://dx.doi.org/10.1016/S0039-9140(01)00507-0[Crossref]
• [24] S.I. Gusev, E.M. Nikolaeva, Zh. Anal. Khim. 21, 166 (1966) (in Russian)
• [25] R.L. Sharma, H.B. Singh, M. Satake, Analyst 111, 551 (1986) http://dx.doi.org/10.1039/an9861100551[Crossref]
• [26] F.I. Lobanov, G.K. Nurtaeva, E.E. Ergozhin, Ekstraktsiya kompleksov ionov metallov s piridinovymi oksiazosoedineniyami (Nauka, Alma-Ata, 1983) (in Russian)
• [27] D. Bin, W. Shuren, W. Qin, F. Jiawei, Kuangwu Yanshi/Journal of Mineralogy & Petrology 15, 97 (1995)
• [28] P. Voznica, J. Havel, L. Sommer, Collection Czech. Chem. Commun. 45, 54 (1980)
• [29] C. Ibraimov, S.T. Talipov, N.B. Babaev, I.M. Nurmatov, Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 24, 669 (1981) (in Russian)
• [30] L. Sommer, M. Langová-Hniličková, Talanta 16, 681 (1969) http://dx.doi.org/10.1016/0039-9140(69)80098-6[Crossref]
• [31] S.L.C. Ferreira, A.C.S. Costa, H.A.S. Andrade, Microchem. J. 44, 63 (1991) http://dx.doi.org/10.1016/0026-265X(91)90077-3[Crossref]
• [32] A.I. Busev, T.N. Zholondkovskaya, L.S. Krysina, N.A. Golubkova, Zh. Anal. Khim. 27, 2165 (1972) (in Russian)
• [33] A.P. Joshi, K.N. Munshi, Mikrochim. Acta 59, 526 (1971) http://dx.doi.org/10.1007/BF01219065[Crossref]
• [34] I.V. Pyatnitskii, A.K. Boryak, L.L. Kolomiets, Zh. Anal. Khim. 41, 2199 (1986) (in Russian)
• [35] N.N. Basargin, A.A. Kafarova, Zavod. Lab. 50, 14 (1984) (in Russian)
• [36] I.V. Pyatnitskii, L.L. Kolomiets, G.M. Popovich, Zh. Anal. Khim. 38, 815 (1983) (in Russian)
• [37] H.A. Mottola, Talanta 11, 715 (1964) http://dx.doi.org/10.1016/0039-9140(64)80095-3[Crossref]
• [38] M.S. Rizk, H.A. Mohamed, Y.M. Issa, M.M. Abu-Agwa, Asian J. Chem. 8, 731 (1996)
• [39] Y. Anjaneyulu, C.S. Kavipurapu, M.R.P. Reddy, P.C. Mouli, Analusis 15, 106 (1987)
• [40] K.B. Gavazov, Z. Simeonova, A. Alexandrov, Talanta 52, 539 (2000) http://dx.doi.org/10.1016/S0039-9140(00)00405-7[Crossref]
• [41] K. Gavazov, V. Lekova, G. Patronov, M. Turkyilmaz, Chem. Anal. (Warsaw) 51, 221 (2006)
• [42] F. Genç, K.B. Gavazov, M. Türkyilmaz, Cent. Eur. J. Chem. 8, 461 (2010) http://dx.doi.org/10.2478/s11532-009-0119-7[Crossref]
• [43] K.B. Gavazov, A.N. Dimitrov, V.D. Lekova, Uspekhi Khim. 76, 187 (2007) (in Russian)
• [44] K.B. Gavazov, V.D. Lekova, A.N. Dimitrov, G.I. Patronov, Cent. Eur. J. Chem. 5, 257 (2007) http://dx.doi.org/10.2478/s11532-006-0053-x[Crossref]
• [45] G.A.E. Mostafa, Talanta 71, 1449 (2007) http://dx.doi.org/10.1016/j.talanta.2006.05.095[Crossref]
• [46] A.G.F. Elsaid, N.M.H. Rizk, A.B.H. Matter, Asian J. Chem. 22, 1736 (2010)
• [47] V. Lekova, P. Racheva, K. Stojnova, A. Dimitrov, K. Gavazov, Chemija 21, 106 (2010)
• [48] M.I. Bulatov, I.P. Kalinkin, Prakticheskoe rukovodstvo po fotokolorimetricheskim i spektrofotometricheskim metodam analiza (Khimiya, Leningrad, 1986) (in Russian)
• [49] T.M. Seward, C.M.B. Henderson, J.M. Charnock, Chem. Geol. 167, 117 (2000) http://dx.doi.org/10.1016/S0009-2541(99)00204-1[Crossref]
• [50] W. Likussar, D.F. Boltz, Anal. Chem. 43, 1265 (1971) http://dx.doi.org/10.1021/ac60304a006[Crossref]
• [51] A. Alexandrov, O. Budevski, A. Dimitrov, J. Radioanal. Chem. 29, 243 (1976) http://dx.doi.org/10.1007/BF02520756[Crossref]
• [52] H.B. Singh, P.S. Kadyan, Bull. Chem. Soc. Jpn. 61, 3689 (1988) http://dx.doi.org/10.1246/bcsj.61.3689[Crossref]

Identifiers

DOI

10.2478/s11532-011-0101-z