High Stokes shift long-wavelength energy gap regulated fluorescence in the series of nitro/dimethylamino-substituted ortho-analogs of POPOP

• Authors: Rodion Iliashenko , Olexiy Zozulia , Andrey Doroshenko
• Languages of publication: EN

Abstracts

EN

A series of novel nitro-substituted ortho-analogs of POPOP was synthesized. Like the most of the other known compounds of this class, the synthesized molecules demonstrate high Stokes shift fluorescence emission owing to the planarization of their molecules at electronic excitation. Significant fluorescence quenching in polar solvents was described as the “energy gap law” action rather than the specific effect of the dialkylamino group excited state twisting. [...]

Keywords

EN

Ortho-analogs of POPOP; High Stokes shift fluorescence; Solvatochromism; Energy gap law; ESS-analysis

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2011
• Volume: 9
• Issue: 6
• Pages: 962-971

Dates

published

1 - 12 - 2011

online

27 - 9 - 2011

Contributors

author

Rodion Iliashenko

• Kharkov V.N. Karazin National University, Kharkov, 61077, Ukraine

author

Olexiy Zozulia

• Kharkov V.N. Karazin National University, Kharkov, 61077, Ukraine

author

Andrey Doroshenko

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Identifiers

DOI

10.2478/s11532-011-0092-9