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Number of results

Journal

2011 | 9 | 5 | 808-812

Article title

Determination of submillimolar concentration of ferrate(VI) in alkaline solutions by amperometric titration

Content

Title variants

Languages of publication

EN

Abstracts

EN
A new amperometric titration method was developed for quantitative determination of ferrate(VI) (FeVIO42−) in the 7.06×10−5−5.73×10−3 M concentration range. Chromium(III) hydroxide solution was used as the titrant. The diffusion current (Id) had a linear relationship with the concentration of ferrate(VI) and slopes were dependent on the concentration of NaOH. The amperometric titration could detect a lower concentration of ferrate(VI) than could potentiometric and colorimetric titrations. The method was applied successfully to determine concentrations of ferrate(VI), generated electrochemically, in strong alkaline solutions. [...]

Publisher

Journal

Year

Volume

9

Issue

5

Pages

808-812

Physical description

Dates

published
1 - 10 - 2011
online
24 - 7 - 2011

Contributors

  • Faculty of Inorganic Substances Technology, Ukraine State Chemical Technological University, 49005, Dniepropetrovsk, Ukraine
  • Chemistry Department, Florida Institute of Technology, Melbourne, Florida, 32901, USA
author
  • Faculty of Inorganic Substances Technology, Ukraine State Chemical Technological University, 49005, Dniepropetrovsk, Ukraine
  • Faculty of Inorganic Substances Technology, Ukraine State Chemical Technological University, 49005, Dniepropetrovsk, Ukraine
author
  • Faculty of Inorganic Substances Technology, Ukraine State Chemical Technological University, 49005, Dniepropetrovsk, Ukraine
  • Faculty of Inorganic Substances Technology, Ukraine State Chemical Technological University, 49005, Dniepropetrovsk, Ukraine
author
  • Nanomaterial Research Centre, Palacky University, 771 46, Olomouc, Czech Republic

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-011-0069-8
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