Partition coefficients of ketones, phenols, aliphatic and aromatic acids, and esters in n-hexane/nitromethane

• Authors: Urszula Kotowska , Valery Isidorov
• Languages of publication: EN

Abstracts

EN

Liquid-liquid partition is used in sample preparation and in countercurrent and liquid-liquid chromatographic separations. Partition coefficients are widely used in toxicology, environmental, and analytical chemistry. The K hn determination procedure for the n-hexane/nitromethane system was optimized and partition coefficients for 99 ketones, esters and trimethylsilyl derivatives of phenols, aliphatic and aromatic acids were determined. For 130 compounds, K hn values were predicted using mathematical relationships between K hn and other physicochemical and structural parameters. [...]

Keywords

EN

Partition coefficients; n-Hexane/nitromethane system; Structure-partitioning relationships

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2011
• Volume: 9
• Issue: 5
• Pages: 813-824

Dates

published

1 - 10 - 2011

online

24 - 7 - 2011

Contributors

author

Urszula Kotowska

• Institute of Chemistry, University of Białystok, ul. Hurtowa 1, 15-399, Bialystok, Poland

author

Valery Isidorov

• Institute of Chemistry, University of Białystok, ul. Hurtowa 1, 15-399, Bialystok, Poland

References

• [1] J. Sangster, Octanol-Water Partition Coefficients: Fundamentals and Physical Chemistry (J. Wiley & Sons Ltd., Chichester, 1997)
• [2] D.W. Connel, Bioaccumulation of Xenobiotic Compounds (CRC Press, Boca Raton, 1990)
• [3] M.H. Abraham, A. Ibrahim, A.M. Zissimos, J. Chromatogr. A 1037, 29 (2004) http://dx.doi.org/10.1016/j.chroma.2003.12.004[Crossref]
• [4] A.M. Zissimos, M.H. Abraham, M.C. Barker, K.J. Box, K.Y. Tam, J. Chem. Soc. Perkin Trans. 2, 470 (2002) [Crossref]
• [5] H. Ahmed, C.F. Poole, J. Chromatogr. A 1104, 82 (2006) http://dx.doi.org/10.1016/j.chroma.2005.11.065[Crossref]
• [6] V.G. Berezkin, V.D. Loshilova, A.G. Pankov, V.D. Yagodovskii, Khromato-Raspredelitelnyi Metod (Nauka, Moscow, 1976) (In Russian)
• [7] I.G. Zenkevich, I.A. Tsibulska, Russ. J. Phys. Chem. 71, 341 (1997) (In Russian)
• [8] V.A. Isidorov, U. Krajewska, J. Jaroszyńska, K. Bal, A. Niesluchowska, L. Vetchinnikova, I. Fuksman, Chem. Anal. (Warsaw) 45, 513 (2000)
• [9] V.A. Isidorov, I.G. Zenkevich, U. Krajewska, E.N. Dubis, J. Jaroszyńska, K. Bal, Phytochem. Anal. 12, 87 (2001) http://dx.doi.org/10.1002/pca.564[Crossref]
• [10] V.A. Isidorov, U. Krajewska, V. Vinogorova, L. Vetchinnikova, I. Fuksman, K. Bal, Biochem. Syst. Ecol. 32, 1 (2004) http://dx.doi.org/10.1016/S0305-1978(03)00175-3[Crossref]
• [11] I.V. Tropnikova, I.G. Zenkevich, A.L. Budantzev, Rastiteln. Res. 35, 1 (1999) (In Russian)
• [12] E.I. Saveleva, I.G. Zenkevich, A.S. Radilov, Russ. J. Anal. Chem. 58, 135 (2003) [Crossref]
• [13] V.A. Isidorov, U. Kotowska, V.T. Vinogorova, Anal. Sci. 21, 483 (2005) http://dx.doi.org/10.2116/analsci.21.1483[Crossref]
• [14] O.K. Ostroukhova, I.G. Zenkevich, O.S. Yukikhin, V.I. Dolzhenko, Russ. J. Appl. Chem. 75, 75 (2002) http://dx.doi.org/10.1023/A:1015521024214[Crossref]
• [15] E.I. Saveleva, I.G. Zenkevich, A.S. Radilov, Russ. J. Anal. Chem. 58, 135 (2003) (In Russian) [Crossref]
• [16] L. Long, Y. Song, J. Wu, L. Lei, K. Huang, B. Long, Anal. Bioanal. Chem. 386, 2169 (2006) http://dx.doi.org/10.1007/s00216-006-0874-7[Crossref]
• [17] S.P. Hong, Ch.H. Lee, S.K. Kim, H.S. Yun, J.H. Lee, K.H. Row, Biotechnol. Bioprocess Eng. 9, 47 (2005) http://dx.doi.org/10.1007/BF02949321[Crossref]
• [18] N. Wu, Y. Liu, M.L. Lee, J. Chromatogr. A 1131, 142 (2006) http://dx.doi.org/10.1016/j.chroma.2006.07.042[Crossref]
• [19] X. Subirats, S.P. Porras, M. Ros’es, E. Kenndler, J. Chromatogr. A 1079, 246 (2005) http://dx.doi.org/10.1016/j.chroma.2005.02.072[Crossref]
• [20] H. Van den Dool, P. Kratz, J. Chromatogr. 11, 463 (1963) http://dx.doi.org/10.1016/S0021-9673(01)80947-X[Crossref]
• [21] R. Kaliszan, Qantitative Structure-Chromatographic Retention Relationships (Wiley, New York, 1987)
• [22] Standard GC retention index library (Sadtler Research Laboratory, Philadelphia, 1986)
• [23] U. Krajewska, Ann. Pol. Chem. Soc. 1, 396 (2003)
• [24] R.P. Adams, Identification of essential oil components by GC/MS (Allured Publishing Corporation, Carol Stream, 1995)
• [25] M. Tuchman, L.D. Bowers, K.D. Fregein, P.J. Crippin, W.J. Crivit, Chromatogr. Sci. 22, 198 (1984)
• [26] T.J. Niwa, Chromatogr. Biomed. Applic. 379, 313 (1986) http://dx.doi.org/10.1016/S0378-4347(00)80688-X[Crossref]
• [27] M.F. Lefevere, B.J. Verhaeghe, D.H. Declerck, J.F. Van Bocxiaer, A.P.J. De Leenheer, Chromatogr. Sci. 27, 23 (1989)

Identifiers

DOI

10.2478/s11532-011-0060-4