N- Hydroxyphthalimide and transition metal salts as catalysts of the liquid-phase oxidation of 1-methoxy-4-(1-methylethyl)benzene with oxygen

• Authors: Beata Orlińska , Iwona Romanowska
• Languages of publication: EN

Abstracts

EN

The oxidation process of 1-methoxy-4-(1-methylethyl)benzene catalysed by N-hydroxyphthalimide (NHPI) or NHPI in combination with Cu(II), Co(II), Mn(II) and Fe(II) salts was studied. The effects of the amount of catalyst and the temperature were determined. 1-Methyl-1-(4-methoxyphenyl)ethyl hydroperoxide was obtained in a yield of 73 mol% when 1-methoxy-4-(1-methylethyl)benzene was oxidised for 3 h at 60°C in acetonitrile as a solvent in the presence of NHPI. 1-(4-Methoxyphenyl)ethanone with high selectivity up to 68–75 mol%, but low yield amounting to 11 mol% was obtained when 1-methoxy-4-(1-methylethyl)benzene was oxidised in the presence of the NHPI/Cu(II) system at 120°C. [...]

Keywords

EN

Catalytic oxidations; NHPI; 1-Methyl-1-(4-methoxyphenyl)ethyl hydroperoxide; 1-(4-Methoxyphenyl)ethanone

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2011
• Volume: 9
• Issue: 4
• Pages: 670-676

Dates

published

1 - 8 - 2011

online

4 - 6 - 2011

Contributors

author

Beata Orlińska

• Department of Chemical Organic Technology and Petrochemistry, Silesian University of Technology, 44-100, Gliwice, Poland

author

Iwona Romanowska

• Department of Chemical Organic Technology and Petrochemistry, Silesian University of Technology, 44-100, Gliwice, Poland

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Identifiers

DOI

10.2478/s11532-011-0048-0