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Number of results

Journal

2011 | 9 | 4 | 605-609

Article title

Activity and stereoselectivity of Ru-based catalyst bearing a fluorinated imidazolinium ligand

Content

Title variants

Languages of publication

EN

Abstracts

EN
Grubbs II generation catalyst (3), bearing a fluorinated imidazolinium ligand, was investigated in cross metathesis (CM), ring closing metathesis (RCM) and ring opening polymerization metathesis (ROMP) for a variety of substrates. Kinetic studies showed reduced stability of the catalyst in methylene chloride following the first 15 minutes of reaction preventing a higher efficiency despite the very high activity. Beneficial solvent effects on the catalyst stability were observed by performing RCM in C6F6. [...]

Publisher

Journal

Year

Volume

9

Issue

4

Pages

605-609

Physical description

Dates

published
1 - 8 - 2011
online
4 - 6 - 2011

Contributors

  • Dipartimento di Chimica, Università di Salerno Via Ponte Don Melillo, I-84084, Fisciano, Salerno, Italy
  • Dipartimento di Chimica, Università di Salerno Via Ponte Don Melillo, I-84084, Fisciano, Salerno, Italy
author
  • Dipartimento di Chimica, Università di Salerno Via Ponte Don Melillo, I-84084, Fisciano, Salerno, Italy
  • Dipartimento di Chimica, Università di Salerno Via Ponte Don Melillo, I-84084, Fisciano, Salerno, Italy
  • Dipartimento di Chimica, Università di Salerno Via Ponte Don Melillo, I-84084, Fisciano, Salerno, Italy

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-011-0034-6
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