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Journal
2011 | 9 | 3 | 386-390
Article title

Synthesis and molecular structure of a novel barium arylspiroboronate ester

Content
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EN
Abstracts
EN
The compound barium bis{bis-(4,6-di-tert-butyl[1,2-benzenediolato(2-)-O,O′]borate)} has been prepared by the addition of 3,5-di-tert-butylcatechol to a solution of boric acid and Ba(OH)2 and characterized by a single crystal X-ray diffraction study. The title compound crystallized in the triclinic space group P-1, with cell parameters a = 13.280(2) Å, b = 15.755(3) Å, and c = 16.980(3) Å, α = 71.691(2)o, β = 79.528(3)o, γ = 80.741(3)o, Z = 1, and V = 3296.1(10) Å3. The structure was solved by direct methods and refined to a final R = 0.0459 for 14370 reflections with I > 2σ(I). One of the arylspiroboronate ester counterions is bound to the barium atom in a rare example of the η1 bonding mode via a single oxygen of one of the catecholato groups. The coordination sphere around the barium is complemented by four molecules of water, one molecule of acetone and two bridging water molecules, connecting to an adjacent barium atom.
Publisher

Journal
Year
Volume
9
Issue
3
Pages
386-390
Physical description
Dates
published
1 - 6 - 2011
online
22 - 3 - 2011
Contributors
  • Mount Allison University
author
  • Mount Allison University
  • Mount Allison University
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-011-0017-7
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