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Journal
2011 | 9 | 2 | 199-205
Article title

Amination-reduction reaction as simple protocol for potential boronic molecular receptors. Insight in supramolecular structure directed by weak interactions

Content
Title variants
Languages of publication
EN
Abstracts
EN
The synthesis of the potential molecular receptors in the amination-reduction reaction has been investigated within the model system comprising (2-formylphenyl)boronic acid and morpholine. The 3-amine substituted benzoxaborole was identified to be the intermediate of the synthesis and the unsubstituted benzoxaborole as the by-product resulting from reduction of the starting material. The insight into the reactivity of the starting materials as well as the intermediate benzoxaborole enabled significant rise in the yield of 2-(aminomethyl) phenylboronic acids synthesis. The solid state structure of 2-(piperidylmethyl)phenylboronic acid has been re-determined, and the description of the molecule and the crystal is given. The supramolecular layer structure directed by the weak C-H…O and C-H…π interactions was identified and scrutinized based on the geometry and Hirshfeld surface analyses
Publisher

Journal
Year
Volume
9
Issue
2
Pages
199-205
Physical description
Dates
published
1 - 4 - 2011
online
17 - 2 - 2011
Contributors
  • Warsaw University of Technology
  • Warsaw University of Technology
  • Warsaw University of Technology
  • Warsaw University of Technology
author
  • Warsaw University of Technology
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-010-0142-8
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