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Number of results

Journal

2011 | 9 | 1 | 149-156

Article title

Sn-Ni-Bi liquid phase thermodynamic properties

Content

Title variants

Languages of publication

EN

Abstracts

EN
Experimental data of bismuth activity coefficients at 1773 K were obtained by isopiestic method and compared to calculated values. Thermodynamic properties of the Sn-Ni-Bi liquid phase were estimated by means of the general solution model and by the methods of Kohler. Description of the ternary liquid phase (Gibbs excess energy dependence on the temperature and the composition) was achieved by using available thermodynamic data of the constitutive binary systems (Ni-Bi, Sn-Bi, Sn-Ni). A comparison between calculated quantities and experimental data wasconducted. The present assessment with thermodynamically optimized values of the system Sn-Ni-Bi (obtained by the CALPHAD approach) was in good agreement. The suggested appearance of a liquid phase miscibility gap at high temperatures is in agreement with the experimental bismuth activity data and with the assessed thermochemical functions. [...]

Publisher

Journal

Year

Volume

9

Issue

1

Pages

149-156

Physical description

Dates

published
1 - 2 - 2011
online
16 - 12 - 2010

Contributors

  • Faculty of Chemistry, University of Plovdiv, Plovdiv, Bulgaria
  • Technical University of Rzeszow, Rzeszow, Poland
  • Faculty of Chemistry, University of Plovdiv, Plovdiv, Bulgaria

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-010-0128-6
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