Sulfoxides in the allylation of aldehydes in the presence of silicon tetrachloride and allyltributylstannane

• Authors: Antonio Massa , Laura Capozzolo , Arrigo Scettri
• Languages of publication: EN

Abstracts

EN

SiCl4 can be conveniently activated by catalytic amounts of dimethyl sulfoxide or other readily-available sulfoxides for the allylation of aromatic, hetero-aromatic and unsaturated aldehydes in the presence of allyltributyl stannane. Chiral aryl methyl sulfoxides have been used to develop asymmetric allylation methods, as well as probe the aldehyde substrate scope.

Keywords

EN

Allylation of aldehydes; Sulfoxides; Lewis base; Silicon tetrachloride; Allyltributylstannane

• Journal: Open Chemistry
• Year: 2010
• Volume: 8
• Issue: 6
• Pages: 1210-1215

Dates

published

1 - 12 - 2010

online

8 - 10 - 2010

Contributors

author

Antonio Massa

• Department of Chemistry, University of Salerno, 84084, Fisciano (Salerno), Italy,

author

Laura Capozzolo

• Department of Chemistry, University of Salerno, 84084, Fisciano (Salerno), Italy

author

Arrigo Scettri

• Department of Chemistry, University of Salerno, 84084, Fisciano (Salerno), Italy

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Identifiers

DOI

10.2478/s11532-010-0099-7