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Number of results

Journal

2010 | 8 | 5 | 1134-1139

Article title

Interfacial transfer of Cd2+ assisted by 4′ - morpholino-acetophenone-4-phenyl-3-thiosemicarbazone across the water/1,2-dichloroethane interface

Content

Title variants

Languages of publication

EN

Abstracts

EN
The assisted transfer of heavy metal ions by interfacial complexation with 4′-morpholinoacetophenone-4-phenyl-3-thiosemicarbazone (MAPPT) at the interface between two immiscible electrolyte solutions (ITIES) was studied by cyclic voltammetry. The voltammograms obtained across the water/1,2-dichloroethane interface using the MAPPT ligand in the organic phase shows that the assisted metal ion transfers have different nature for different ions. The quasi-reversible voltammetric peak of the Cd2+ ion was obtained and is discussed in detail. The dependence of the half-wave transfer potential on MAPPT concentration showed that the equilibrium is effectively displaced towards a 1:3 (metal:ligand) stoichiometry with an association constant of log β o =15.46 (±0.11) for the Cd2+ ion, corresponding to the TIC/TID mechanism. [...]

Publisher

Journal

Year

Volume

8

Issue

5

Pages

1134-1139

Physical description

Dates

published
1 - 10 - 2010
online
5 - 9 - 2010

Contributors

author
  • Chemistry Department, Selcuk University, 42099, Meram/Konya, Turkey
author
  • Chemistry Department, Selcuk University, 42099, Meram/Konya, Turkey

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-010-0089-9
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