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Journal
2010 | 8 | 5 | 1134-1139
Article title

Interfacial transfer of Cd2+ assisted by 4′ - morpholino-acetophenone-4-phenyl-3-thiosemicarbazone across the water/1,2-dichloroethane interface

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Abstracts
EN
The assisted transfer of heavy metal ions by interfacial complexation with 4′-morpholinoacetophenone-4-phenyl-3-thiosemicarbazone (MAPPT) at the interface between two immiscible electrolyte solutions (ITIES) was studied by cyclic voltammetry. The voltammograms obtained across the water/1,2-dichloroethane interface using the MAPPT ligand in the organic phase shows that the assisted metal ion transfers have different nature for different ions. The quasi-reversible voltammetric peak of the Cd2+ ion was obtained and is discussed in detail. The dependence of the half-wave transfer potential on MAPPT concentration showed that the equilibrium is effectively displaced towards a 1:3 (metal:ligand) stoichiometry with an association constant of log β o =15.46 (±0.11) for the Cd2+ ion, corresponding to the TIC/TID mechanism. [...]
Publisher
Journal
Year
Volume
8
Issue
5
Pages
1134-1139
Physical description
Dates
published
1 - 10 - 2010
online
5 - 9 - 2010
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-010-0089-9
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