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2010 | 8 | 5 | 965-991
Article title

Isomers in the chemistry of iron coordination compounds

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Abstracts
EN
The coordination chemistry of iron covers a wide field, as shown by a survey covering the crystallographic and structural data of almost one thousand and three hundred coordination complexes. About 6.7% of these complexes exist as isomers and are summarized in this review. Included are distortion (96.6%) and cis - trans (3.4%) isomers. These are discussed in terms of the coordination about the iron atom, bond length and interbond angles. Distortion isomers, differing only by degree of distortion in Fe-L, Fe-L-Fe and L-Fe-L parameters, are the most common. Iron is found in the oxidation states zero, +2 and +3 of which +3 is most common. The stereochemistry around iron centers are tetrahedral, five - coordinated (mostly trigonal - bipyramid) and six - coordinated. The most common ligands have O and N donor sites.
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Publisher
Journal
Year
Volume
8
Issue
5
Pages
965-991
Physical description
Dates
published
1 - 10 - 2010
online
5 - 9 - 2010
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