Isomers in the chemistry of iron coordination compounds

• Authors: Milan Melnik , Mária Kohútová
• Languages of publication: EN

Abstracts

EN

The coordination chemistry of iron covers a wide field, as shown by a survey covering the crystallographic and structural data of almost one thousand and three hundred coordination complexes. About 6.7% of these complexes exist as isomers and are summarized in this review. Included are distortion (96.6%) and cis - trans (3.4%) isomers. These are discussed in terms of the coordination about the iron atom, bond length and interbond angles. Distortion isomers, differing only by degree of distortion in Fe-L, Fe-L-Fe and L-Fe-L parameters, are the most common. Iron is found in the oxidation states zero, +2 and +3 of which +3 is most common. The stereochemistry around iron centers are tetrahedral, five - coordinated (mostly trigonal - bipyramid) and six - coordinated. The most common ligands have O and N donor sites.

Keywords

EN

Iron; Complexes; Distortion; Cis - trans; Isomers

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2010
• Volume: 8
• Issue: 5
• Pages: 965-991

Dates

published

1 - 10 - 2010

online

5 - 9 - 2010

Contributors

author

Milan Melnik

• Department of Ecology, Faculty of Humanistic and Natural Sciences, University of Presov, 081 16, Presov, Slovak Republic

author

Mária Kohútová

• Department of Chemical Theory of Drugs, Faculty of Pharmacy, Comenius University, 832 32, Bratislava, Slovak Republic

References

• [1] M. Melník, I. Ondrejkovičová, V. Vančová, C.E. Holloway, Rev. Inorg. Chem. 17, 55 (1997)
• [2] M. Melník, V. Vančová, I. Ondrejkovičová, C.E. Holloway, Rev. Inorg. Chem. 18, 1 (1998) [Crossref]
• [3] M. Melník, Coord. Chem. Rev. 47, 239 (1982) http://dx.doi.org/10.1016/0010-8545(82)85033-9[Crossref]
• [4] L. Mazarella, C. Pellechia, C.A. Mattia, V. De Felice, R. Puliti, J. Coord. Chem. 14, 191 (1986) http://dx.doi.org/10.1080/00958978608073907[Crossref]
• [5] S. Mitra, C.L. Raston, A. H. White, Aust. J. Chem. 31, 547 (1978) http://dx.doi.org/10.1071/CH9780547[Crossref]
• [6] P.C. Healy, A.H. White, J. Chem. Soc. Dalton Trans. 1163 (1972) [Crossref]
• [7] J.L. Hoard, G.H. Cophen, M.D. Glick, J. Am. Chem. Soc. 89, 1992 (1967) http://dx.doi.org/10.1021/ja00985a004[Crossref]
• [8] W.R. Scheidt, M.G. Finnegan, Acta Crystallogr., Sect. C 45, 1214 (1982) http://dx.doi.org/10.1107/S0108270189000715[Crossref]
• [9] J.M. Bassett, D.E. Berny, G.K. Barker, M. Green, J.A.K. Howard, F.G.A. Stone, J. Chem. Soc., Dalton Trans. 1003 (1979) [Crossref]
• [10] H.C. Freeman, G.H.W. Millburn, C.E. Nockolds, R. Mason, G.B. Robertson, G.A. Rusholme, Acta Crystallogr., Sect. B 30, 886 (1974) http://dx.doi.org/10.1107/S0567740874004006[Crossref]
• [11] A.R. Hermes, G.S. Girolami, Inorg. Chem. 27, 1775 (1988) http://dx.doi.org/10.1021/ic00283a021[Crossref]
• [12] J.E. Barclay, A. Hills, O.L. Hughes, G.J. Leigh, J. Chem. Soc., Dalton Trans. 2871 (1988) [Crossref]
• [13] E. Mulliez, G. Guillot-Edelheit, P. Leduc, J.C. Chottard, C. Bois, A. Bousseksom, W. Nitschke, New J. Chem. 16, 435 (1992)
• [14] M. Bacci, C.A. Ghilardi, A. Orlandini, Inorg. Chem. 23, 2798 (1984) http://dx.doi.org/10.1021/ic00186a017[Crossref]
• [15] G.D. Fallon, P.J. Nichols, B.O. West, J. Chem. Soc. Dalton Trans. 2271 (1986) [Crossref]
• [16] J. Strouse, S.W. Layton, Ch.E. Strouse, J. Amer. Chem. Soc. 99, 562 (1977) http://dx.doi.org/10.1021/ja00444a041[Crossref]
• [17] O. Baumgartner, Z. Kristallogr. 174, 253 (1986) http://dx.doi.org/10.1524/zkri.1986.174.1-4.253[Crossref]
• [18] B.A. Stork-Blaisse, G.C. Verschoor, C. Romers, Acta Crystallogr., Sect. B 28, 948 (1984)
• [19] M.E. Garcia Posse, M.A. Juri, P J. Aymonino, O.E. Piro, H.A. Negri, E.E. Castellano, Inorg. Chem. 23, 948 (1984) http://dx.doi.org/10.1021/ic00175a030[Crossref]
• [20] P. Bonhôte, M. Ferigo, H. Stoeckli-Evans, W. Marty, Acta Crystallogr. Sect. C 49, 2102 (1993) http://dx.doi.org/10.1107/S010827019300424X[Crossref]
• [21] J.D. Oliver, D.F. Mullica, B.B. Hutchinson, W.O. Milligan, Inorg. Chem. 19, 165 (1980) http://dx.doi.org/10.1021/ic50203a034[Crossref]
• [22] H.-R. Chang, J.K. McCusker, H. Toftlund, S.R. Wilson, A.X. Trautwein, H. Winkler, D.N. Hendrickson, J. Amer. Chem. Soc. 112, 6814 (1990) http://dx.doi.org/10.1021/ja00175a012[Crossref]
• [23] K. Kirschbaum, K. Greiwe, K. Müller, H. Strasdeit, B. Krebs, G. Henkel, Z. Naturforsch. 45b, 497 (1990)
• [24] H.J. Küppers, K. Wieghardt, B. Nuber, J. Weiss, E. Bill, A.X. Trautwein, Inorg. Chem. 26, 3762 (1987) http://dx.doi.org/10.1021/ic00269a028[Crossref]
• [25] a)_P. Gauzerh, Y. Jeannin, C. Rocchiccioli-Deticheff, F. Valentini, J. Coord. Chem. 129, 39 (1987)
• [26] b)_C.L. Raston, A.H. White, J. Chem. Soc., Dalton Trans. 1915 (1976) [Crossref]
• [27] I.C. Paul, G.A. Sim, J. Chem. Soc. 1097 (1965) [Crossref]
• [28] W.R. Scheidt, Y.J. Lee, M.G. Finnegan, Inorg. Chem. 20, 2337 (1981) http://dx.doi.org/10.1021/ic50221a079[Crossref]
• [29] B.E.A. Abadi, R.A. Palmer, B.W. Fitzsimmons, J. Cryst. Spectr. Res. 18, 35 (1988) http://dx.doi.org/10.1007/BF01171023[Crossref]
• [30] A. Elmali, Y. Elerman, I. Svoboda, H. Fuesss, Acta Crystallogr., Sect. C 49, 1365 (1993) http://dx.doi.org/10.1107/S0108270193000617[Crossref]
• [31] D.M.L. Goodgame, D.J. Williams, R.E.P. Winpenny, Inorg. Chim. Acta 166, 159 (1989) http://dx.doi.org/10.1016/S0020-1693(00)80803-8[Crossref]
• [32] I.A. Baidina, P.A. Stabnikov, V.I. Alekseev, I.G. Igumenov, S.V. Borisov, Zh. Strukt. Khim. 27, 102 (1986) (In Russian)
• [33] M.B. Hossain, M.A.F. Jalal, B.A. Benson, C.L. Barnes, D. van der Helm, J. Amer. Chem. Soc. 109, 4948 (1987) http://dx.doi.org/10.1021/ja00250a031[Crossref]
• [34] C.L. Barnes, M.B. Hossain, M.A.F. Jalal, D.L. Eng-Wilmot, S.L. Graysen, B.A. Benson, S.K. Agarval, R.R. Mocherla, D. van der Helm, Acta Crystallogr., Sect. C 41, 341 (1985) http://dx.doi.org/10.1107/S0108270185003857[Crossref]
• [35] M. Teintze, M.B. Hossain, C.L. Barnes, J. Leong, D. van der Helm, Biochemistry 20, 6446 (1981) http://dx.doi.org/10.1021/bi00525a025[Crossref]
• [36] U. Müller, Acta Crystallogr., Sect. B, 33 (1977) 2197 http://dx.doi.org/10.1107/S0567740877008000[Crossref]
• [37] S.-H. Cho, D. Whang, K.-N. Han, K. Kim, Inorg. Chem. 31, 519 (1992) http://dx.doi.org/10.1021/ic00029a034[Crossref]
• [38] S.-H. Cho, D. Whang, K.-N. Han, K. Kim, Bull. Korean Chem. Soc. 12, 107 (1991)
• [39] J.C.A. Boeyens, A.G.S. Forbes, R.D. Hancock, K. Wieghardt, Inorg. Chem. 24, 2926 (1984) http://dx.doi.org/10.1021/ic00213a011[Crossref]
• [40] W.R. Scheidt, S.R. Osvath, Y.J. Lee, J. Amer. Chem. Soc. 109, 1958 (1987) http://dx.doi.org/10.1021/ja00241a010[Crossref]
• [41] R. Quinn, J.S. Valentine, M.P. Byrn, Ch.E. Strouse, J. Amer. Chem. Soc. 109, 3301 (1987) http://dx.doi.org/10.1021/ja00245a019[Crossref]
• [42] D.K. Geiger, V. Chumplang, W.R. Scheidt, Inorg. Chem. 24, 4736 (1985) http://dx.doi.org/10.1021/ic00220a061[Crossref]
• [43] M.K. Safo, G.P. Gupta, F.A. Walter, W.R. Scheidt, J. Amer. Chem. Soc. 113, 5497 (1991) http://dx.doi.org/10.1021/ja00015a001[Crossref]
• [44] W.R. Scheidt, D.K. Geiger, R.G. Hayes, G. Lang, J. Amer. Chem. Soc. 105, 2625 (1983) http://dx.doi.org/10.1021/ja00347a018[Crossref]
• [45] A. Terzis, S. Filippakis, D. Mentzafós, V. Petrouleas, A. Malliaris, Inorg. Chem. 23, 334 (1984) http://dx.doi.org/10.1021/ic00171a013[Crossref]
• [46] A. Cousson, F. Nectoux, E.N. Rizhalla, Acta Crystallogr., Sect. C 48, 1354 (1992) http://dx.doi.org/10.1107/S0108270192002877[Crossref]
• [47] J.F. Endicott, B. Durham, M.D. Glick, T.J. Anderson, J.M. Kuszaj, W.G. Schmonsees, K.P. Balakrishnan, J. Amer. Chem. Soc. 103, 1431 (1981) http://dx.doi.org/10.1021/ja00396a024[Crossref]
• [48] T. Mashiko, M.E. Kastner, K. Spartalian, W.R. Scheidt, Ch.A. Reed, J. Amer. Chem. Soc. 100, 6354 (1978) http://dx.doi.org/10.1021/ja00488a013[Crossref]
• [49] P.J. Kellett, M.J. Pawlik, L.F. Taylor, R.G. Thompson, M.A. Levestik, O.P. Anderson, S.H. Strauss, Inorg. Chem. 28, 440 (1989) http://dx.doi.org/10.1021/ic00302a014[Crossref]
• [50] A.J. Conti, R.K. Chadha, K.M. Sena, A.I. Rheingold, D.N. Hendrickson, Inorg. Chem. 32, 2670 (1993) http://dx.doi.org/10.1021/ic00064a017[Crossref]
• [51] M.D. Timten, D.N. Hendrickson, Inorg. Chem. 32, 2670 (1993) http://dx.doi.org/10.1021/ic00064a017[Crossref]
• [52] J.P. Battioni, I. Artaud, D. Duprè, P. Leduc, I. Akhrem, D. Mansery, J. Fischer, R. Weiss, I. Morgenstern-Badarou, J. Amer. Chem. Soc. 108, 5598 (1986) http://dx.doi.org/10.1021/ja00278a039[Crossref]
• [53] T. Mashiko, Ch.A. Reed, K.J. Haller, M.E. Kastner, W.R. Scheidt, J. Amer. Chem. Soc. 103, 5758 (1981) http://dx.doi.org/10.1021/ja00409a024[Crossref]
• [54] A.A. Aruffó, B.D. Santarsiero, V. Shomuker, E.C. Lingafelter, Acta Crystallogr., Sect. C 40, 1693 (1984) http://dx.doi.org/10.1107/S0108270184009185[Crossref]
• [55] P. Doppelt, J. Fischer, R. Weiss, Croat. Chim. Acta 57, 507 (1984)
• [56] E.B. Lobkovskii, M.Yu. Antipin, A.P. Borisov, V.D. Machaev, K.N. Semenenko, Yu. Struchkov, Koord. Khim. 6, 1267 (1980) (In Russian)
• [57] Z. Olejnik, T. Lis, I. Ondrejkovičová, Acta Crystyallogr. Sect. C 51, 2246 (1995) http://dx.doi.org/10.1107/S0108270195006354[Crossref]
• [58] W. Xin, W.T. Pennington, J.C. Fanning, Wuji Huaxue Xuebao (J. Inorg. Chem.) 7, 275 (1991)
• [59] N.A. Ryabova, V.I. Ponomarev, V.V. Zelentsov, L.O. Atovmyan, Kristallografiya 27, 101 (1982) (In Russian)
• [60] N.A. Ryabova, V.I. Ponomarev, V.V. Zelentsov, L. O. Atovmyan, Kristallografiya 27, 279 (1982) (In Russian)
• [61] N.A. Ryabova, V.I. Ponomarev, L.O. Atovmyan, V.V. Zelentsov, V.I. Shijilov, Koord. Khim. 4, 119 (1978) (In Russian)
• [62] X. Wang, W.T. Pennington, D.L. Ankers, J.C. Fanning, Polyhedron 11, 2253 (1992) http://dx.doi.org/10.1016/S0277-5387(00)83704-3[Crossref]
• [63] B. Chiari, O. Pievenasa, T. Tarantelli, P.F. Zanazzi, Inorg. Chem. 21, 1396 (1982) http://dx.doi.org/10.1021/ic00134a025[Crossref]
• [64] B.S. Snyder, G.S. Patterson, A.J. Abrahamson, R.H. Holm, J. Amer. Chem. Soc. 111, 5214 (1989) http://dx.doi.org/10.1021/ja00196a031[Crossref]
• [65] L. Leluk, B. Ježowska-Trzebiatowska, T. Lis, Polyhedron 11, 1923 (1992) http://dx.doi.org/10.1016/S0277-5387(00)83741-9[Crossref]
• [66] N. Kitajima, N. Tamura, M. Tanaka, Y. Moro-oka, Inorg. Chem. 31, 3342 (1992) http://dx.doi.org/10.1021/ic00042a002[Crossref]
• [67] A. Salifóglou, A. Simopoulos, A. Kostikas, R.W. Dunham, M.G. Kanatzidis, D. Coucouvanis, Inorg. Chem. 27, 3394 (1988) http://dx.doi.org/10.1021/ic00292a026[Crossref]
• [68] R.A. Jones, A.L. Stuart, J.L. Atwood, W.E. Hunter, R.D. Rogers, Organometalics 1, 1721 (1982) http://dx.doi.org/10.1021/om00072a036[Crossref]
• [69] E. Keller, H. Vahrenkamp, Chem. Ber. 112, 1626 (1979) http://dx.doi.org/10.1002/cber.19791120513[Crossref]
• [70] Ch. Glidewell, M.E. Herman, M.B. Hursthouse, L.L. Johnson, M. Motewalli, J. Chem. Res.(S) 212 (1988)
• [71] E.J. Laskowski, R.B. Frankel, W.O. Gillum, G.L. Papaefthymiou, J. Renaud, J.A. Ibers, P.H. Holm, J. Amer. Chem. Soc. 100, 5322 (1978) http://dx.doi.org/10.1021/ja00485a013[Crossref]
• [72] T.D.P. Stack, J.A, Weigel, R.H. Holm, Inorg. Chem. 29, 3745 (1990) http://dx.doi.org/10.1021/ic00344a022[Crossref]
• [73] M.A. Whitener, J.K. Bashkin, K.S. Hager, J.J. Girerd, E. Gamp, N. Edelstein, R.H. Holm, J. Amer. Chem. Soc. 108, 5607 (1986) http://dx.doi.org/10.1021/ja00278a040[Crossref]
• [74] N.V. Gerbeleu, A.S. Bacanov, G.A. Timko, Yu.T. Struchkov, K.M. Indrichan, G.A. Popovich, Dokl. Akad. Nauk SSSR 293, 364 (1987) (In Russian); A.S. Bacanov, Yu.T. Struchkov, G.A. Timko, Koord. Khim. 14, 266 (1988) (In Russian)
• [75] B. A. Katz, Ch.E. Strouse, Inorg. Chem. 19, 658 (1980) http://dx.doi.org/10.1021/ic50205a017[Crossref]
• [76] G.F. Volodina, L.I. Petuchov, A.V. Ablov, N.V. Gerbeleu, Dokl. Akad. Nauk SSSR 218, 1351 (1974) (In Russian)
• [77] N.A. Bailey, D. Cummins, E.D. McKenzie, J.M. Worthington, Inorg. Chim. Acta 18, L13 (1976); N.A. Bailey, D. Cummins, E.D. McKenzie, J.M. Worthington, Inorg. Chim. Acta 50, 111 (1981) http://dx.doi.org/10.1016/S0020-1693(00)95565-8[Crossref]
• [78] J.P. Collman, J.L. Hoard, N. Kim, G. Lang, Ch.A. Reed, J. Amer. Chem. Soc. 97, 2676 (1975) http://dx.doi.org/10.1021/ja00843a015[Crossref]
• [79] N. Li, Z. Su, P. Coppens, J. Landrum, J. Amer. Chem. Soc. 112, 7294 (1990) http://dx.doi.org/10.1021/ja00176a032[Crossref]
• [80] I.P. Lavrentyev, L.G. Korableva, E.A. Lavrentyeva, G.A. Nifonova, M.I. Khidekel, L.G. Gusatovskaya, T.I. Larkina, L.D. Arutyunyan, O.S. Filipenko, V.I. Ponomarev, L.O. Atovmyan, Koord. Khim. 5, 1484 (1979) (In Russian)
• [81] M. Konno, M. Mikani-Kido, Bull. Chem. Soc. Jpn. 64, 339 (1991) http://dx.doi.org/10.1246/bcsj.64.339[Crossref]
• [82] B. Gallois, J.A. Real, Ch. Hauw, J. Zarembowich, Jr., Inorg. Chem. 29, 1152 (1990) http://dx.doi.org/10.1021/ic00331a009[Crossref]
• [83] J.A. Real, B. Gallois, T. Granier, F. Suez-Panamá, J. Zarembovich, Jr., Inorg. Chem. 31, 4972 (1992) http://dx.doi.org/10.1021/ic00050a013[Crossref]
• [84] A.T. Baker, N.Y. Ferguson, H.A. Goodwin, A.D. Rae, Aust. J. Chem. 42, 623 (1989) http://dx.doi.org/10.1071/CH9890623[Crossref]
• [85] A.M. Greenaway, E. Sinn, J. Amer. Chem. Soc. 100, 8080 (1978) http://dx.doi.org/10.1021/ja00494a009[Crossref]
• [86] M. Mikami, M. Kono, Y. Saito, Acta Crystallogr., Sect. B 36, 275 (1980) http://dx.doi.org/10.1107/S0567740880003093[Crossref]
• [87] A.M. Greenaway, Ch.J. O’ Connor, A. Schrock, E. Sinn, Inorg. Chem. 18, 2692 (1979) http://dx.doi.org/10.1021/ic50200a011[Crossref]
• [88] B.A. Katz, Ch.E. Strouse, J. Amer. Chem. Soc. 101, 6214 (1979) http://dx.doi.org/10.1021/ja00515a010[Crossref]
• [89] A.T. Baker, H.A. Goodwin, A.D. Rae, Inorg. Chem. 26, 3513 (1987) http://dx.doi.org/10.1021/ic00268a020[Crossref]
• [90] C. Lecomte, R.H. Blessing, P. Copens, A. Tabard, J. Amer. Chem. Soc. 108, 6942 (1986) http://dx.doi.org/10.1021/ja00282a019[Crossref]
• [91] F. Ceconi, M. Di Varia, S. Midollini, A. Orlandini, L. Sacconi, Inorg. Chem. 20, 3423 (1981) http://dx.doi.org/10.1021/ic50224a053[Crossref]
• [92] Ch.A. Reed, T. Mashiko, W.R. Scheidt, K. Spartatian, G. Lang, J. Amer. Chem. Soc. 102, 2302 (1980) http://dx.doi.org/10.1021/ja00527a028[Crossref]
• [93] M.P. Byrn, Ch.E. Strouse, J. Amer. Chem. Soc. 113, 2501 (1991) http://dx.doi.org/10.1021/ja00007a025[Crossref]
• [94] W.R. Scheidt, D.K. Geiger, K.J. Haller, J. Amer. Chem. Soc. 104, 495 (1982) http://dx.doi.org/10.1021/ja00366a019[Crossref]
• [95] B.N. Figgis, E.S. Kucharski, J.M. Raynes, P.A. Reynolds, J. Chem. Soc., Dalton Trans. 1597 (1990)
• [96] J. Albertsson, L. Oskarsson, Acta Crystallogr., Sect. B 33 1871 (1977) http://dx.doi.org/10.1107/S0567740877007237[Crossref]
• [97] J. Albertson, L. Oskarsson, K. Staahl, C. Svensson, I. Ymén, Acta Crystallogr., Sect.B 37, 50 (1981) http://dx.doi.org/10.1107/S0567740881002173[Crossref]
• [98] J.G. Leipoldt, P. Coppens, Inorg. Chem. 12, 2269 (1973) http://dx.doi.org/10.1021/ic50128a012[Crossref]
• [99] J. Albertsson, L. Oskarsson, M. Nygren, Acta Crystallogr., Sect. B 35, 1473 (1979) http://dx.doi.org/10.1107/S0567740879006786[Crossref]
• [100] J. Albertsson, L. Oskarsson, K. Staahl, Acta Chem. Scand., Sect. A 36, 783 (1982) http://dx.doi.org/10.3891/acta.chem.scand.36a-0783[Crossref]
• [101] Y. Maeda, H. Oshio, K. Toriumi, Y. Takashima, J. Chem. Soc., Dalton Trans. 1227 (1991) [Crossref]
• [102] Y. Maeda, H. Oshio, Y. Takashima, M. Mikurya, M. Hidala, Inorg. Chem. 25, 2958 (1986); H. Oshio, K. Toriumi, Y. Maeda, Y. Takashima, Inorg. Chem. 30, 4252 (1991) http://dx.doi.org/10.1021/ic00237a008[Crossref]
• [103] B.J. Kennedy, A.C. McGrath, K.S. Murray, B.W. Shelton, A.H. White, Inorg. Chem. 26, 483 (1987) http://dx.doi.org/10.1021/ic00251a003[Crossref]
• [104] Y. Maeda, H. Oshio, K. Toriumi, Y. Takashima, J. Chem. Soc., Dalton Trans. 1227 (1991) [Crossref]
• [105] N.A. Ryabova, V.I. Ponomarev, V.V. Zelentsov, L.O. Atovmyan, Kristallografiya 26, 101 (1981) (In Russian)
• [106] V.I. Ponomarev, L.D. Arutyunyan, L.O. Atovmyan, Kristallografiya 29, 910 (1984) (In Russian)
• [107] Seung-Mo Oh, D.N. Hendrickson, K.L. Hassett, R.E. Davis, J. Amer. Chem, Soc. 106, 7984 (1984); Seung-Mo Oh, D.N. Hendrickson, K.L. Hassett, R.E. Davis, J. Amer. Chem, Soc. 107, 8009 (1985) http://dx.doi.org/10.1021/ja00337a063[Crossref]
• [108] P. Excoffon, J.J. Laugier, B. Lamotte, Inorg. Chem. 30, 3075 (1991) http://dx.doi.org/10.1021/ic00015a026[Crossref]

Identifiers

DOI

10.2478/s11532-010-0083-2