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Journal
2010 | 8 | 4 | 797-805
Article title

Kinetics of base hydrolysis of α-amino acid esters catalyzed by palladium(II) piperazine complex

Content
Title variants
Languages of publication
EN
Abstracts
EN
The kinetics of base hydrolysis of glycine, histidine, and methionine methyl esters in the presence of [Pd(pip)(H2O)2]2+ complex, where pip is piperazine, is studied in aqueous solutions, at T = 25°C, and I = 0.1 mol dm−3. The rate of ester hydrolysis for glycine methyl ester is studied at different temperature and dioxane/water solutions of different compositions. The kinetic data are fit under the assumption that the hydrolysis proceeds in one step. The activation parameters for the base hydrolysis of the complexes are evaluated [...]
Publisher
Journal
Year
Volume
8
Issue
4
Pages
797-805
Physical description
Dates
published
1 - 8 - 2010
online
17 - 6 - 2010
References
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-010-0047-6
Identifiers
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