Equilibrium and kinetic study of the proton transfer reactions between nitroalkanes and strong organic bases - phosphazenes in tetrahydrofuran solvent

• Authors: Iwona Binkowska , Włodzimierz Gałęzowski , Arnold Jarczewski
• Languages of publication: EN

Abstracts

EN

Proton transfer reactions rates between carbon acids 1-nitro-1-(4-nitrophenyl)ethane (NPNE), 2-methyl-1-nitro-1-(4-nitrophenyl)propane (MNPNP)) and phosphazenes (BEMP, BTPP, P1-t-Oct) in tetrahydrofuran have been measured, and the activation parameters were determined. The results are compared with those previously obtained for P1-t-Bu phosphazene, guanidines and amidines. [...]

Keywords

EN

Proton/deuteron transfer; Carbon acids; Phosphazene bases

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2010
• Volume: 8
• Issue: 3
• Pages: 582-586

Dates

published

1 - 6 - 2010

online

25 - 4 - 2010

Contributors

author

Iwona Binkowska

• Faculty of Chemistry, Adam Mickiewicz University, 60-780, Poznan, Poland

author

Włodzimierz Gałęzowski

• Faculty of Chemistry, Adam Mickiewicz University, 60-780, Poznan, Poland

author

Arnold Jarczewski

• Faculty of Chemistry, Adam Mickiewicz University, 60-780, Poznan, Poland

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Identifiers

DOI

10.2478/s11532-010-0044-9