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Number of results

Journal

2010 | 8 | 3 | 513-518

Article title

Theory of reverse scan square-wave voltammetry influenced by the kinetics of reactant adsorption

Content

Title variants

Languages of publication

EN

Abstracts

EN
A model of electrode reaction complicated by slow adsorption of the reactant is developed for square-wave voltammetry with inverse scan direction. The relationship between the dimensionless net peak current and the logarithm of dimensionless rate constant of adsorption is a curve with a minimum and a maximum. For this reason the ratio of real net peak current and the square-root of frequency is a non-linear function of the logarithm of frequency and exhibits either a maximum or a minimum. The frequency of extreme serves for the estimation of the rate constant: log(k ads /D 1/2 ) = log(k*ads )crit + 0.5 log f crit , where (k*ads )crit is a critical dimensionless rate constant of adsorption. Square-wave voltammetry is sensitive to the kinetics of adsorption if k ads 2 cm s−1 [...]

Publisher

Journal

Year

Volume

8

Issue

3

Pages

513-518

Physical description

Dates

published
1 - 6 - 2010
online
25 - 4 - 2010

Contributors

  • Department of Marine and Environmental Research, “Rudjer Bošković” Institute, P.O. Box 180, HR-10002, Zagreb, Hrvatska (Croatia)
  • Department of Marine and Environmental Research, “Rudjer Bošković” Institute, P.O. Box 180, HR-10002, Zagreb, Hrvatska (Croatia)

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-010-0034-y
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