Properties of ibuprofen ion-selective electrodes based on the ion pair complex of tetraoctylammonium cation

• Authors: Joanna Lenik , Cecylia Wardak
• Languages of publication: EN

Abstracts

EN

Ibuprofen membrane electrodes based on different plasticizers: diisobutyl phthalate (DIBP), o-nitrophenyloctyl ether (o-NPOE), dioctyl sebacate (DOS) and tetraoctylammonium 2-(4-isobutylphenyl)propionate were prepared. All electrodes show: a near Nernstian slope of characteristic (58.3–60.9 mV decade−1) in the measurement range (10−4–10−1 mol L−1), limit of detection (5.0×10−5 mol L−1), really long lifetime (12 months), dependence of the electrode potential on pH (5.5–9.0), reproducibility of potential (0.6–1.2 mV) and selectivity coefficients in relation to some organic and inorganic anions. The electrodes were applied for the determination of ibuprofen in tablets by the calibration curve method and the standard addition method. [...]

Keywords

EN

Potentiometric determination; Ion-selective electrodes; Pharmaceutical formulation; Ibuprofen; Tetraoctylammonium chloride

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2010
• Volume: 8
• Issue: 2
• Pages: 382-391

Dates

published

1 - 4 - 2010

online

23 - 3 - 2010

Contributors

author

Joanna Lenik

• Faculty of Chemistry, Maria Curie-Skłodowska University, 20-031, Lublin, Poland

author

Cecylia Wardak

• Faculty of Chemistry, Maria Curie-Skłodowska University, 20-031, Lublin, Poland

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Identifiers

DOI

10.2478/s11532-010-0005-3