Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl

• Authors: Beata Orlińska , Jan Zawadiak
• Languages of publication: EN

Abstracts

EN

The oxidation processes of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl with oxygen in the presence of a catalyst, composed of copper(II) chloride and tetrabutylammonium bromide, were investigated. It was found that, in essence, only one isopropyl group undergoes oxidation, and obtained mixtures contained mainly peroxide, alcohol, ketone and only small amounts of hydroperoxide. [...]

Keywords

EN

Catalytic oxidation; 2,6-Diisopropylnaphthalene; 4,4′-Diisopropylbiphenyl; Peroxides

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2010
• Volume: 8
• Issue: 2
• Pages: 285-290

Dates

published

1 - 4 - 2010

online

23 - 3 - 2010

Contributors

author

Beata Orlińska

• Department of Chemical Organic Technology and Petrochemistry, Silesian University of Technology, Gliwice, 44-100, Poland

author

Jan Zawadiak

• Department of Chemical Organic Technology and Petrochemistry, Silesian University of Technology, Gliwice, 44-100, Poland

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Identifiers

DOI

10.2478/s11532-009-0134-8