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Journal
2010 | 8 | 1 | 207-213
Article title

Simultaneous spectrophotometric determination of phenanthridine, phenanthridinone and phenanthridine N-oxide using multivariate calibration methods

Content
Title variants
Languages of publication
EN
Abstracts
EN
The multivariate calibration methods, partial least squares (PLS) and principle component regression (PCR) have been used to determine phenanthridine, phenanthridinone and phenanthridine N-oxide in spiked human plasma samples. Resolution of binary and ternary mixtures of analytes with minimum sample pre-treatment and without analyte separation has been successfully achieved analyzing the UV spectral data. The net analyte signal (NAS) concept was also used to calculate multivariate analytical figures of merit such as limit of detection, selectivity and sensitivity. The simultaneous determination of three analytes was possible by PLS and PCR processing of sample absorbance in the 210–355 nm region. Good recoveries were obtained for both synthetic mixtures and spiked human plasma samples. [...]
Publisher

Journal
Year
Volume
8
Issue
1
Pages
207-213
Physical description
Dates
published
1 - 2 - 2010
online
16 - 2 - 2010
Contributors
  • Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 51666-16471, Iran
author
  • Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 51666-16471, Iran
  • Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz branch, Tabriz, 1655, Iran
  • Department of Medicinal Chemistry, School of Pharmacy, Tabriz University of Medical Sciences, Tabriz, 51664-14766, Iran, rashidi@tbzmed.ac.ir
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-009-0121-0
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