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Journal
2009 | 7 | 4 | 731-738
Article title

The study of cyclooctene oxidation with molecular oxygen catalyzed by VSi2

Content
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EN
Abstracts
EN
The catalytic effect of VSi2 on initial stages of the liquid-phase oxidation of cyclooctene by molecular oxygen was studied. The vanadium disilicide influences on the oxidation process in the presence of hydroperoxide. VSi2 takes part in a radical formation stage by catalysis of hydroperoxide decomposition reaction. The catalyst was investigated before and after reaction using FTIR spectroscopy. From the data obtained, the kinetic model of the catalytic oxidation process was proposed and the equation for the reaction rate was derived. The equation has described all observed dependences of reaction rate on the concentration of reactants and content of catalyst. [...]
Keywords
Publisher

Journal
Year
Volume
7
Issue
4
Pages
731-738
Physical description
Dates
published
1 - 12 - 2009
online
6 - 10 - 2009
Contributors
author
  • Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79013, Lviv, Ukraine, o_makota@polynet.lviv.ua
author
  • Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79013, Lviv, Ukraine
author
  • Faculty of Chemistry, Maria Curie-Sklodowska University, 20-031, Lublin, Poland
  • Faculty of Chemistry, Maria Curie-Sklodowska University, 20-031, Lublin, Poland
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-009-0096-x
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