Modified silica surface by phenylboronic acid derivatives as effective sugar sensor

• Authors: Joanna Kurczewska , Grzegorz Schroeder
• Languages of publication: EN

Abstracts

EN

Silica surface was modified with phenylboronic acid derivatives. The structures of the functionalized supports were characterized by FT-IR spectroscopy, 13C CP/MAS NMR spectrometry, elemental and thermogravimetric analysis. The solid supports were effectively applied as artificial receptors for sugars in aqueous solutions. Alizarin Red S. (ARS) was used to detect colour change upon carbohydrate (sugar) binding. The association constants of the supports studied-ARS complex and the functionalized silica-sugar (glucose) complex were calculated. The parameters obtained were comparable with those for the phenylboronic acids used for the silica gel modification. The competitive binding of the functionalized silica surface with ARS and sugar were studied by UV/VIS measurements. [...]

Keywords

EN

Silica surface modification; Boronic acid derivatives; Diols; Alizarin Red S.

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2009
• Volume: 7
• Issue: 4
• Pages: 697-701

Dates

published

1 - 12 - 2009

online

6 - 10 - 2009

Contributors

author

Joanna Kurczewska

• Faculty of Chemistry, Adam Mickiewicz University, 60-780, Poznań, Poland

author

Grzegorz Schroeder

• Faculty of Chemistry, Adam Mickiewicz University, 60-780, Poznań, Poland

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Identifiers

DOI

10.2478/s11532-009-0080-5