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Abstracts
A series of organic/inorganic hybrid materials containing the single-molecule magnet [Mn12(CH3COO)16(H2O)4O12]·2CH3COOH·4H2O with the photochromic compounds azobenzene or disperse red 1 cast into polymethyl methacrylate films was prepared. To understand the photomodulation of analogous mixtures’ AC susceptibility, we investigated the molecular alignment based on Weigert’s effect accompanying cycles of cis-trans photoisomerization by alternate irradiations with polarized UV and visible light. Polarized electronic spectra of the hybrid materials demonstrated gradually increasing anisotropy. These features suggest interactions between photochromic compounds and the Mn12 complex in polymethyl methacrylate. [...]
Publisher
Journal
Year
Volume
Issue
Pages
690-696
Physical description
Dates
published
1 - 12 - 2009
online
6 - 10 - 2009
Contributors
author
- Department of Chemistry, Faculty of Science, Tokyo University of Science, 162-8601, Tokyo, Japan
author
- Department of Chemistry, Faculty of Science, Tokyo University of Science, 162-8601, Tokyo, Japan
author
- Department of Chemistry, Faculty of Science, Tokyo University of Science, 162-8601, Tokyo, Japan
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-009-0075-2