PL EN


Preferences help
enabled [disable] Abstract
Number of results
Journal
2009 | 7 | 4 | 900-908
Article title

Use of the sulfide minerals pyrite and chalcopyrite as electrochemical sensors in non-aqueous solutions. The potentiometric titration of weak acids in alcohols

Content
Title variants
Languages of publication
EN
Abstracts
EN
Natural monocrystalline pyrite and chalcopyrite were examined as new indicator electrodes for the potentiometric titration of weak acids in tert-butanol and iso-propanol. The electrodes investigated demonstrated a linear dynamic response for p-toluenesulfonic acid concentrations in the range from 0.1 to 0.001 M, with a Nernstian slope of 48 mV per decade for pyrite in tert-butanol. Sodium methylate, potassium hydroxide and tetrabutylammonium hydroxide (TBAH) proved to be suitable titrating agents. The response time was less than 12 s and the lifetime of the electrodes was higher than 1 year. The advantages of the electrodes are long-term stability, rapid response, reproducibility, easy preparation and low cost. [...]
Keywords
Publisher

Journal
Year
Volume
7
Issue
4
Pages
900-908
Physical description
Dates
published
1 - 12 - 2009
online
6 - 10 - 2009
Contributors
  • Department of Chemistry, Faculty of Sciences, University of Kragujevac, 34 000, Kragujevac, Serbia
  • Faculty of Chemistry, University of Belgrade, 11 000, Belgrade, Serbia
  • Technical High School, 37000, Kruševac, Serbia
  • Department of Chemistry, Faculty of Sciences, University of Kragujevac, 34 000, Kragujevac, Serbia, randjel@kg.ac.rs
References
  • [1] A.P. Kreshkov, N.T. Smolova, T.J. Burmistrova, J. Phys. Chem. 50, 987 (1976)
  • [2] A.P. Kreshkov, Analytic Chemistry of Non-Aqueous Solution (Khimiya, Moscow, 1982) 187 (in Russian)
  • [3] A. Aslan, Y. Erdogan, A. Demirbaš, S. Karslioglu, Farmazie 52, 309 (1997)
  • [4] M. Alkan et al., Molecules 12, 1805 (2007) http://dx.doi.org/10.3390/12081805[Crossref]
  • [5] Ya.I. Korenman, T.N. Yermolaeva, Analyst 120, 2387 (1995) http://dx.doi.org/10.1039/an9952002387[Crossref]
  • [6] J.S. Fritz, L.W. Marple, Anal. Chem. 34, 921 (1962) http://dx.doi.org/10.1021/ac60188a014[Crossref]
  • [7] I.M. Kolthoff, M.K. Chantooni, Jr., Anal. Chem. 50, 1440 (1978) http://dx.doi.org/10.1021/ac50033a016[Crossref]
  • [8] K. Ertekin, S. Alp, I. Yalcin, Dyes and Pigments 65, 33 (2005) http://dx.doi.org/10.1016/j.dyepig.2004.06.011[Crossref]
  • [9] H. Yüksek, Z. Osak, M. Alkan, Ş. Bahçeci, M. Özdemir, Molecules 9, 232 (2004) http://dx.doi.org/10.3390/90400232[Crossref]
  • [10] L.W. Marple, G.J. Scheppers, Anal. Chem. 38, 553 (1966) http://dx.doi.org/10.1021/ac60236a008[Crossref]
  • [11] L.W. Marple, J.S. Fritz, Anal. Chem. 35, 1223 (1963) http://dx.doi.org/10.1021/ac60202a004[Crossref]
  • [12] L.W. Marple, J.S. Fritz, Anal. Chem. 34, 796 (1962) http://dx.doi.org/10.1021/ac60187a025[Crossref]
  • [13] E. Bosch, C. Rodés, M. Rosés, Electroanalysis 3, 365 (1991) http://dx.doi.org/10.1002/elan.1140030420[Crossref]
  • [14] J.S. Fritz, F.E. Gainer, Talanta 15, 939 (1968) http://dx.doi.org/10.1016/0039-9140(68)80094-3[Crossref]
  • [15] K. Izutsu, Electrochemistry in Nonaqueous Solution (Wiley-VCS, Germany, 2002) http://dx.doi.org/10.1002/3527600655[Crossref]
  • [16] H. Yüksek et al., Asian J. Chem. 17, 195, (2005)
  • [17] H. Yksek, M. Alkan, Ş. Bahçeci, Molbank M462 (2006)
  • [18] Ş. Bahçeci, H. Yüksek, Z. Ocak, C. Köksal, M. Özdemir, Acta Chim. Slov. 49, 783 (2002)
  • [19] Ş. Bahçeci, H. Yüksek, Z. Ocak, I. Azakli, M. Özdemir, Collect. Czech. Chem. Commun. 67, 1215 (2002) http://dx.doi.org/10.1135/cccc20021215[Crossref]
  • [20] A.A. Hakan, Y. Samin, Acta Chim. Slov. 51, 273 (2004)
  • [21] A.H. Aktaş, G. Yaşar, G.Ö. Alsancak, Ş. Demirci, Turk. J. Chem. 25, 501 (2001)
  • [22] J. Hine, M. Hine, J. Am. Chem. Soc. 74, 5266 (1952) http://dx.doi.org/10.1021/ja01141a009[Crossref]
  • [23] M. Yalçin, S. Tanyolaç I. Kizilcikli, A. Tavman, Turk. J. Chem. 22, 155 (1998)
  • [24] T. Gündüz, E. Kiliç G. Özkan, Analyst 113, 1017 (1988) http://dx.doi.org/10.1039/an9881301017[Crossref]
  • [25] E. Bosch, C. Rodés, M. Rosés, Electroanalysis 3, 365 (1991) http://dx.doi.org/10.1002/elan.1140030420[Crossref]
  • [26] E. Canel, M. Taştekin, O. Atakol, E. Kiliç, Turk. J. Chem. 27, 77 (2003)
  • [27] J.M. Andrés, C. Romero, Fuel 67, 1305 (1988) http://dx.doi.org/10.1016/0016-2361(88)90055-5[Crossref]
  • [28] G. Johansson, Talanta 11, 789 (1964) http://dx.doi.org/10.1016/0039-9140(64)80105-3[Crossref]
  • [29] B.G. Cooksey, B. Metters, J.M. Ottaway, D.W. Whymark, Talanta 20, 371 (1973) http://dx.doi.org/10.1016/0039-9140(73)80165-1[Crossref]
  • [30] A.S. Saraç, B. Ustamehmetoglu, C. Erbil, Polym Bulletin 32, 91 (1994) http://dx.doi.org/10.1007/BF00297419[Crossref]
  • [31] C. Özeroglu, H. Cankurtaran, Indian Journal Chem. 40B, 438 (2001)
  • [32] C. Özeroglu, A.S. Saraç, Asian J. Chem. 18(3), 1808 (2006)
  • [33] B. Karlberg, G. Johansson, Talanta 16, 1545 (1969) http://dx.doi.org/10.1016/0039-9140(69)80215-8[Crossref]
  • [34] E.J. Greenhow, B.F. Al-Mudarris, Talanta 22, 417 (1975) http://dx.doi.org/10.1016/0039-9140(75)80089-0[Crossref]
  • [35] C.J. Lintner, R.H. Schleif, T. Higuchi, Anal. Chem. 22, 534 (1950) http://dx.doi.org/10.1021/ac60040a007[Crossref]
  • [36] K. Izutsu, T. Nakamura, T. Arai, M. Ohmaki, Electroanalysis 7, 884 (1955) http://dx.doi.org/10.1002/elan.1140070916[Crossref]
  • [37] K. Izutsu, M. Ohmaki, Talanta 43, 643 (1996) http://dx.doi.org/10.1016/0039-9140(95)01799-2[Crossref]
  • [38] K. Izutsu, H. Yamamoto, Anal. Sci. 12, 905 (1996) http://dx.doi.org/10.2116/analsci.12.905[Crossref]
  • [39] Lj.V. Mihajlović, R.P. Mihajlović, M.M. Antonijević, B.V. Vukanović, Talanta 64, 879 (2004) http://dx.doi.org/10.1016/j.talanta.2004.03.061[Crossref]
  • [40] R.P. Mihajlović, Z.D. Stanić, J. Solid State Electrochem. 9, 558 (2005) http://dx.doi.org/10.1007/s10008-004-0591-0[Crossref]
  • [41] Lj.V. Mihajlović, S.D. Nikolić-Mandić, B.V. Vukanović, R.P. Mihajlović, J. Solid State Electrochem. 13, 895 (2009) http://dx.doi.org/10.1007/s10008-008-0625-0[Crossref]
  • [42] Lj. Mihajlović, S. Nikolić-Mandić, B. Vukanović, R. Mihajlović, Anal. Sci. 25, 437 (2009) http://dx.doi.org/10.2116/analsci.25.437[Crossref]
  • [43] A.P. Kreshkov, L.N. Bykova, N.A. Kazaryan, Kislotno-osnovnoe titrovanie v nevodnykh rastvorakh (Khimia, Moskow, 1967) (in Russian)
  • [44] M. Antonijević, B. Vukanović, R. Mihajlović, Talanta 39, 809 (1992) http://dx.doi.org/10.1016/0039-9140(92)80100-R[Crossref]
  • [45] N. Oyama, T. Hirokawa, S. Yamaguchi, N. Ushizawa, T. Shimomura, Anal. Chem. 59, 258 (1987) http://dx.doi.org/10.1021/ac00129a009[Crossref]
  • [46] D. Kuruoglu, E. Canel, Sh. Memon, M. Yilmaz, E. Kiliç, Anal. Sci. 19, 217 (2003) http://dx.doi.org/10.2116/analsci.19.217[Crossref]
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-009-0074-3
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.