Determination of Alizarin Red S using a novel B-Z oscillation system catalyzed by a tetraazamacrocyclic complex

• Authors: Gang Hu , Lulu Chen , Jinfeng Zhang , Panpan Chen , Wei Wang , Jimei Song , Lingguang Qiu , Juan Song , Lin Hu
• Languages of publication: EN

Abstracts

EN

A new and convenient method for the determination of Alizarin Red S by the perturbations caused by different amounts of Alizarin Red S on a novel B-Z oscillating system is proposed. This new type Belousov-Zhabotinskii involves a macrocyclic copper(II) complex [CuL](ClO4)2 as catalyst and malic acid as the substrate. The ligand L in the complex is 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene. It is found that the relationship between the change in the oscillation amplitude and the logarithm of the Alizarin Red S concentration in the range of 1.5 × 10−7 to 1 × 10−3 M fits a polynomial model: ΔA = 659 + 184.2 log [Alizarin Red S]+ 12.9 log2 [Alizarin Red S]. The RSD obtained with ten samples is 4.4%. The probable mechanism involving the perturbation of Alizarin Red S on the oscillating chemical system is also discussed. [...]

Keywords

EN

Kinetic determination; Alizarin Red S; Tetraazamacrocyclic complex; Belousov-Zhabotinskii reaction

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2009
• Volume: 7
• Issue: 3
• Pages: 291-297

Dates

published

1 - 9 - 2009

online

21 - 6 - 2009

Contributors

author

Gang Hu

• Department of Chemistry, Anhui University, Hefei, 230039, P. R. China

author

Lulu Chen

• Department of Chemistry, Anhui University, Hefei, 230039, P. R. China

author

Jinfeng Zhang

• Department of Chemistry, Anhui University, Hefei, 230039, P. R. China

author

Panpan Chen

• Department of Chemistry, Anhui University, Hefei, 230039, P. R. China

author

Wei Wang

• Department of Chemistry, Anhui University, Hefei, 230039, P. R. China

author

Jimei Song

• Department of Chemistry, Anhui University, Hefei, 230039, P. R. China

author

Lingguang Qiu

• Department of Chemistry, Anhui University, Hefei, 230039, P. R. China

author

Juan Song

• Department of Chemistry, Anhui University, Hefei, 230039, P. R. China

author

Lin Hu

• Institute of Applied Chemistry, East China Jiaotong University, Nanchang, 330013, P. R. China

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Identifiers

DOI

10.2478/s11532-009-0042-y