A hydroxyaminophosphane derived from 2-imidazolidone and its unusual structure in solution

• Authors: Olaf Kühl , Waltraud Heiden
• Languages of publication: EN

Abstracts

EN

A novel hydroxyamino phosphane was synthesised through the reaction of 2-imidazolidinone with ClPPh2 and subsequently reaction of the resulting bisphosphino derivative with the Grignard reagent BrMgC5H11. The interaction of the pentyl substituent with one of the two phosphino groups and the structure in solution is shown by multinuclear NMR-spectroscopy.. [...]

Keywords

EN

Grignard reaction; Hydroxyaminophosphane; Phosphane; Reduction; „Through-space”-coupling

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2009
• Volume: 7
• Issue: 3
• Pages: 281-284

Dates

published

1 - 9 - 2009

online

21 - 6 - 2009

Contributors

author

Olaf Kühl

• Institute of Biochemistry, University of Greifswald, D-17489, Greifswald, Germany

author

Waltraud Heiden

• Institute of Biochemistry, University of Greifswald, D-17489, Greifswald, Germany

References

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Identifiers

DOI

10.2478/s11532-009-0021-3