Sol-gel bioactive glass-ceramics Part II: Glass-ceramics in the CaO-SiO2-P2O5-MgO system

• Authors: Lachezar Radev , Vladimir Hristov , Irena Michailova , Bisserka Samuneva
• Languages of publication: EN

Abstracts

EN

Ceramics, with basic composition based on the CaO-SiO2-P2O5-MgO system with different Ca+ Mg/P+Si molar ratio (R), were prepared via polystep sol-gel technique. The structure of the obtained ceramic materials has been studied by XRD, FTIR spectroscopy, and SEM. X-ray diffraction showed the presence of akermanite and HA for the sample with R = 1.68 and Mg substituted β-TCP and silicocarnotite for the sample with R = 2.16, after thermal treatment at 1200°C/2 h. The obtained results are in good agreement with FTIR. In vitro test for bioactivity in static condition proved that the carbonate containing hydroxyapatite (CO3HA) can be formed on the surface of the synthesized samples. CO3HA consisted of both A- and B-type CO 32− ions. SEM micrographs depicted different forms of HA particles, precipitated on the surface after soaking in 1.5 simulated body fluid (SBF). [...]

Keywords

EN

Sol-gel; Bioceramics; In vitro bioactivity

• Journal: Open Chemistry
• Year: 2009
• Volume: 7
• Issue: 3
• Pages: 322-327

Dates

published

1 - 9 - 2009

online

21 - 6 - 2009

Contributors

author

Lachezar Radev

• University of Chemical Technology and Metallurgy, 1756, Sofia, Bulgaria,

author

Vladimir Hristov

• University of Chemical Technology and Metallurgy, 1756, Sofia, Bulgaria

author

Irena Michailova

• University of Chemical Technology and Metallurgy, 1756, Sofia, Bulgaria

author

Bisserka Samuneva

• University of Chemical Technology and Metallurgy, 1756, Sofia, Bulgaria

References

• [1] L.L. Hench, et al., J. Biomed. Mater. Res. 2, 117 (1972)
• [2] T. Kokubo, et al., J. Biomed. Mater. Res. 24, 331 (1990) http://dx.doi.org/10.1002/jbm.820240306[Crossref]
• [3] A. Oyane, et al., J. Biomed. Mater. Res. 65A, 188 (2003) http://dx.doi.org/10.1002/jbm.a.10482[Crossref]
• [4] C. Ohtsuki, T. Kokubo, T. Yamamuro, J. Non-Cryst. Solids 143, 84 (1992) http://dx.doi.org/10.1016/S0022-3093(05)80556-3[Crossref]
• [5] M. Vallet-Regi, et al., Chem. Mater. 17, 1874 (2005) http://dx.doi.org/10.1021/cm047956j[Crossref]
• [6] A. Ramila, F. Balas, M. Vallet-Regi, Chem. Mater. 14, 542 (2002) http://dx.doi.org/10.1021/cm0110876[Crossref]
• [7] D. Arcos, J. Pena, M. Vallet-Regi, Chem. Mater. 15, 4132 (2003) http://dx.doi.org/10.1021/cm031074n[Crossref]
• [8] D. Arcos, D.C. Greenspan, M. Vallet-Regi, Chem. Mater. 14, 1515 (2002) http://dx.doi.org/10.1021/cm011119p[Crossref]
• [9] J. Perez-Pariente, F. Balas, M. Vallet-Regi, Chem. Mater. 12, 750 (2000) http://dx.doi.org/10.1021/cm9911114[Crossref]
• [10] M. Vallet-Regi, C.V. Ragel, A.J. Salinas, Eur. J. Inorg. Chem. 1029 (2003)
• [11] T. Kokubo, Biomaterials 12, 155 (1991) http://dx.doi.org/10.1016/0142-9612(91)90194-F[Crossref]
• [12] S.B. Cho, et al., Biomaterials 18, 1479 (1997) http://dx.doi.org/10.1016/S0142-9612(97)00084-7[Crossref]
• [13] J. Shyu, J. Wu, J. Mater. Sci. 29, 3167 (1994) http://dx.doi.org/10.1007/BF00356658[Crossref]
• [14] A. Balamurugan, et al., J. Biomed. Mater. Res. Part B: Appl. Biomater. 83B, 546 (2007) http://dx.doi.org/10.1002/jbm.b.30827[Crossref]
• [15] D.-M. Liu, Material Chemistry and Physics 36, 294 (1994) http://dx.doi.org/10.1016/0254-0584(94)90045-0[Crossref]
• [16] S. Agathopoulos, et al., J. Non-Cryst. Solids 352, 322 (2006) http://dx.doi.org/10.1016/j.jnoncrysol.2005.12.003[Crossref]
• [17] B. Yu, K. Liang, S. Gu, Ceramics International 29, 695 (2003) http://dx.doi.org/10.1016/S0272-8842(02)00219-5[Crossref]
• [18] P. Alizadeh, B.E. Yekta, T. Javadi, J. Eur. Ceram. Soc. 28, 1569 (2008) http://dx.doi.org/10.1016/j.jeurceramsoc.2007.10.007[Crossref]
• [19] P. Alizadeh, B. Eftekhary, A. Gervei, J. Eur. Ceram. Soc. 24, 3529 (2004) http://dx.doi.org/10.1016/j.jeurceramsoc.2003.11.028[Crossref]
• [20] H-L. Ren, et al., Chem. Phys. Lett. 292, 317 (1998) http://dx.doi.org/10.1016/S0009-2614(98)00676-9[Crossref]
• [21] R.G. Hill, M. Patel, D.J. Wood, In: W. Bonfield, G.W. Castings, K.E. Tanner (Eds), Bioceremics, (Buttrerworth-Heinemann, London, 1991) 79
• [22] R. Hill, D. Wood, J. Mater. Sci: Mater. Med. 6, 311 (1995) http://dx.doi.org/10.1007/BF00120298[Crossref]
• [23] A. Cliford, R. Hill, J. Non.-Cryst. Solids 196, 346 (1996) http://dx.doi.org/10.1016/0022-3093(95)00611-7[Crossref]
• [24] B. Samuneva, et al., J. Sol-Gel Sci. Techn. 13, 255 (1998) http://dx.doi.org/10.1023/A:1008647404796[Crossref]
• [25] B. Samuneva, et al., J. Sol-Gel Sci. Techn. 26, 1203 (2003) http://dx.doi.org/10.1023/A:1020716404034[Crossref]
• [26] B. Samuneva, et al., J. Sol-Gel Sci. Techn. 26, 273 (2003) http://dx.doi.org/10.1023/A:1020767603299[Crossref]
• [27] V. Hristov, et al., In: E. Balabanova, I. Dragieva (Eds), Proceedings of the Eight Workshop “Nanosrtuctured Materials Application and Inovation Transfer”, Nanoscience & Nanotechnology, 20–22 Nov., Sofia, Bulgaria, (Heron Press Science Series, Sofia, 2007) 235
• [28] L. Guo, M. Huang, X. Zhang, J. Mater. Sci.: Mater. Med. 14, 817 (2003) http://dx.doi.org/10.1023/A:1025048724330[Crossref]
• [29] S. Kannan, et al., J. Am. Ceram. Soc. 89(9), 2757 (2006) [Crossref]
• [30] A. Martines, I. Izquierdo-Barba, M. Vallet-Regi, Chem. Mater. 12, 3080 (2000) http://dx.doi.org/10.1021/cm001107o[Crossref]
• [31] P. McMillan, American Mineralogist 69, 622 (1984)
• [32] P. McMillan, American Mineralogist 69, 645 (1984)
• [33] S.R. Federman, et al., 17 CECIMat, Congresso Brasiliero de Engenharia e Clencia dos Materials, Brasil (2006)
• [34] J. Roman, et al., Biomaterials 22, 2013 (2001) http://dx.doi.org/10.1016/S0142-9612(00)00387-2[Crossref]
• [35] I. Rehman, W. Bonfield, J. Mater. Sci.: Mater. Med. 8, 1 (1997) http://dx.doi.org/10.1023/A:1018570213546[Crossref]
• [36] I.R. Gibson, et al., J. Mater. Sci.: Mater. Med. 12, 799 (2000) http://dx.doi.org/10.1023/A:1008905613182[Crossref]
• [37] P.N. de Aza, et al., Chem. Mater. 9, 916 (1997) http://dx.doi.org/10.1021/cm9604266[Crossref]
• [38] P.N. de Aza, et al., Chem. Mater. 9, 912 (1997) http://dx.doi.org/10.1021/cm960425d[Crossref]
• [39] A.M. Hofmeister, E. Keppel, A.K. Speck, Mon. Not. R. Astron. Soc. 345, 16 (2003) http://dx.doi.org/10.1046/j.1365-8711.2003.06899.x[Crossref]
• [40] I. de Lima, A.M. Costa, I.N. Bastos, Mater. Res. 9, 1 (2006)
• [41] Zh. Yang, et al., J. Mater. Chem. 15, 1807 (2005) http://dx.doi.org/10.1039/b418015c[Crossref]
• [42] M.P. Mahabole, et al., Bull. Mater. Sci. 28, 535 (2005) http://dx.doi.org/10.1007/BF02706339[Crossref]
• [43] D.E. Smeulders, M.A. Wilson, L. Amstrong, Ind. Eng. Chem. Ress. 40, (2001)
• [44] G.A. Stanciu, et al., J. Biomed. & Pharmac. Eng. 1, 34 (2007)
• [45] J. Ou, et al., Biomed. Mater. 3, 1 (2008) http://dx.doi.org/10.1088/1748-6041/3/1/015015[Crossref]
• [46] H. Lin, et al., J. Ceram. Soc. Jpn. 104, 291 (1996) [Crossref]
• [47] N. Hijon, et al., Chem. Mater. 16, 1451 (2004) http://dx.doi.org/10.1021/cm031164s[Crossref]
• [48] I. Hofmann, et al., J. Am. Ceram. Soc. 90, 821 (2007) http://dx.doi.org/10.1111/j.1551-2916.2007.01500.x[Crossref]
• [49] N. Pleshko, A. Boskey, R. Mendelsohn, Biophys. J. 60, 786 (1991) http://dx.doi.org/10.1016/S0006-3495(91)82113-0[Crossref]
• [50] A. Balamurugan, et al., Ceramics-Silikaty 50, 27 (2006)
• [51] Y. Lee, et al., J. Mater. Sci. 42, 7843 (2007) http://dx.doi.org/10.1007/s10853-007-1629-3[Crossref]
• [52] X. Chen, et al., J. Mater. Sci.: Mater. Med. 19, 1257 (2008) http://dx.doi.org/10.1007/s10856-007-3233-0[Crossref]
• [53] S. Ni, J. Chang, L. Chou, J. Mater. Sci: Mater. Med. 19, 359 (2008) http://dx.doi.org/10.1007/s10856-007-3186-3[Crossref]

Identifiers

DOI

10.2478/s11532-009-0014-2