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Journal
2009 | 7 | 3 | 410-414
Article title

Synthesis of Co3O4 nanoparticles by oxidation-reduction method and its magnetic characterization

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EN
Abstracts
EN
Without any surfactant, antiferromagnetic Co3O4 nanoparticles were synthesized successfully for the first time by means of an oxidation-reduction method with cobalt sulfate as starting material, which was oxidized to cobalt salt by NaNO3 after alkalinizing with NaOH. Morphological, structural, spectroscopic and magnetic characterization of the product were done by SEM, TEM, XRD, and VSM, respectively. The average crystallite size (on the base of line profile fitting method), D and σ, is estimated as 30 ± 6 nm. Some anomalous magnetic properties and their enhanced effect have been observed in Co3O4 antiferromagnetic nanocrystallites, including a bias field, coercivity, permanent magnetic moments and an open loop. These phenomena are attributed to the unidirectional anisotropy which is caused by the exchange coupling between AFM and FM layers, the existence of the spin glass like surface spins of Co3O4 nanoparticles due to size effects and surface-area effect. [...]
Publisher

Journal
Year
Volume
7
Issue
3
Pages
410-414
Physical description
Dates
published
1 - 9 - 2009
online
21 - 6 - 2009
Contributors
author
  • Department of Chemistry, Fatih University, Hadimköy, 34500, Istanbul, Turkey
author
  • Department of Chemistry, Fatih University, Hadimköy, 34500, Istanbul, Turkey, hbaykal@fatih.edu.tr
author
  • Department of Physics, Fatih University, Hadimköy, 34500, Istanbul, Turkey
author
  • Department of Physics, Fatih University, Hadimköy, 34500, Istanbul, Turkey
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-009-0012-4
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