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Journal
2009 | 7 | 1 | 54-58
Article title

Adsorption of lanthanides(III) from aqueous solutions by fullerene black modified with di(2-ethylhexyl)phosphoric acid

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EN
Abstracts
EN
Fullerene black (FB) - a product of electric arc graphite vaporization after extraction of fullerenes - was modified with the di(2-ethylhexyl)phosphoric acid (D2EHPA). The distribution of D2EHPA between FB and aqueous HNO3 solutions has been studied. The effect of HNO3 concentration in the aqueous phase and that of D2EHPA concentration in the sorbent phase on the adsorption of microquantities of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y nitrates from HNO3 solutions by D2EHPA-modified FB are considered. The stoichiometry of the sorbed complexes has been determined by the slope analysis method. The efficiency of lanthanides’ adsorption increases with an increase in the element atomic number. A considerable synergistic effect has been observed upon the addition of the neutral bidentate tetraphenylmethylenediphosphine dioxide ligand to D2EHPA in the sorbent phase. [...]
Publisher
Journal
Year
Volume
7
Issue
1
Pages
54-58
Physical description
Dates
published
1 - 3 - 2009
online
23 - 12 - 2008
References
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-008-0093-5
Identifiers
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