Novel organic material with potential NLO application - electronic and spectroscopic properties

• Authors: B.B. Koleva , T. Kolev , R. Nikolova , Y. Zagraniarsky , M. Spiteller
• Languages of publication: EN

Abstracts

EN

Novel dicyanoisophorone derivative, (E)-2-(3-(4-aminostyryl)-5,5-dimethylcyclohex-2-enylidene)malononitrile, is synthesized and its structure elucidated by means of conventional and linear polarized IR-spectroscopy of oriented colloids in nematic host, 1H, 13C, 1H, 1H-COSY NMR, HPLC tandem ESI MS-MS spectrometry, UV-VIS and thermal methods. Ab initio and DFT level of theory are used to theoretically obtain the electronic structure and optical properties, both in ground and exited state, of the compound. [...]

Keywords

EN

(E)-2-(3-(4-aminostyryl)-5,5-dimethylcyclohex-2-enylidene)malononitrile; Synthesis; Spectroscopic properties and structural elucidation; potential NLO material

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2008
• Volume: 6
• Issue: 4
• Pages: 592-599

Dates

published

1 - 12 - 2008

online

28 - 10 - 2008

Contributors

author

B.B. Koleva

• Lehrstuhl für Analytische Chemie, Ruhr-Universität Bochum, 44780, Bochum, Germany

author

T. Kolev

• Institut für Umweltforschung, Universität Dortmund, 44221, Dortmund, Germany

author

R. Nikolova

• Department of Organic Chemistry, Sofia University St. Kl. Ohridski, 1164, Sofia, Bulgaria

author

Y. Zagraniarsky

• Department of Organic Chemistry, Sofia University St. Kl. Ohridski, 1164, Sofia, Bulgaria

author

M. Spiteller

• Institut für Umweltforschung, Universität Dortmund, 44221, Dortmund, Germany

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Identifiers

DOI

10.2478/s11532-008-0061-0