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Journal
2008 | 6 | 3 | 419-428
Article title

Kinetic studies for the esterification of acetic acid with epichlorohydrin over an anion exchange resin catalyst

Content
Title variants
Languages of publication
EN
Abstracts
EN
The kinetics of the esterification reaction between acetic acid and epichlorohydrin catalysed by Purolite A-520E strong basic anion exchange resin was studied. The effects of certain parameters such as stirring speed, particle diameter, temperature, catalyst amount and molar ratio between reactants were experimentally determined. It was found that the overall reaction rate is intrinsically kinetically controlled. The partial orders of reaction with respect to catalyst, acetic acid and epichlorohydrin were determined. A reaction mechanism is proposed. Based on chromatographic data and taking into account the partial orders of reaction, a more detailed kinetic model is suggested. [...]
Publisher

Journal
Year
Volume
6
Issue
3
Pages
419-428
Physical description
Dates
published
1 - 9 - 2008
online
11 - 8 - 2008
Contributors
author
  • Departement of Organical and Biochemical Engineering, The Faculty of Chemical Engineering, “Gh. Asachi” Technical University of Iassy, D. Mangeron Street, Iasi, 700050, Romania, eimuresan@yahoo.co.uk
  • Departement of Organical and Biochemical Engineering, The Faculty of Chemical Engineering, “Gh. Asachi” Technical University of Iassy, D. Mangeron Street, Iasi, 700050, Romania
author
  • Ecole Nationale Superieure de Chimie de Montpellier 8, rue de l’Ecole Normale, Montpellier, Cedex, 5, France
  • Departament of Natural and Synthetic Polymers, The Faculty of Chemical Engineering, “Gh. Asachi” Technical University of Iassy, D. Mangeron street, 71A, Iasi, 700050, Romania
author
  • Departament of Natural and Synthetic Polymers, The Faculty of Chemical Engineering, “Gh. Asachi” Technical University of Iassy, D. Mangeron street, 71A, Iasi, 700050, Romania
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-008-0046-z
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