Sol-gel preparation and characterization of non-substituted and Sr-substituted lanthanum cobaltates

• Authors: Sigute Cizauskaite , Aivaras Kareiva
• Languages of publication: EN

Abstracts

EN

This paper reports on the results concerning the sol-gel preparation and characterization of Sr-substituted perovskite lanthanum cobaltates La1−xSrxCoO3−δ (x = 0.0, 0.25, 0.5 and 0.75). The metal ions, generated by dissolving starting materials in diluted acetic acid were complexed by 1,2-ethanediol to obtain the precursors for the non-substituted and Sr-substituted LaCoO3. The influence of the synthesis temperature, heating time and the amount of substituent on the phase purity of La1−xSrxCoO3−δ were investigated. The phase transformations, composition and micro-structural features in the gels and polycrystalline samples were studied by thermal analysis (TG/DTA), infrared spectroscopy (IR), powder X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). [...]

Keywords

EN

Sol-gel synthesis; Perovskite cobaltates; LaCoO3 ; Strontium; Substitution effect

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2008
• Volume: 6
• Issue: 3
• Pages: 456-464

Dates

published

1 - 9 - 2008

online

11 - 8 - 2008

Contributors

author

Sigute Cizauskaite

• Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

author

Aivaras Kareiva

• Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

References

• [1] F.S. Galasso, Perovskites and High Tc Superconductors, Gordon and Breach Science Publishers, New York, 1990
• [2] E.J. Baran, Catal. Today 8, 133 (1990) http://dx.doi.org/10.1016/0920-5861(90)87015-U[Crossref]
• [3] L.B. Archer, C.D. Chandler, R. Kingsborough, M.J. Hampden-Smith, J. Mater. Chem. 5, 151 (1995) http://dx.doi.org/10.1039/jm9950500151[Crossref]
• [4] A.S. Bhalla, R. Guo, R. Roy, Mater. Res. Innov. 4, 3 (2000) http://dx.doi.org/10.1007/s100190000062[Crossref]
• [5] J.P. Attfield, Int. J. Inorg. Mater. 3, 1147 (2001) http://dx.doi.org/10.1016/S1466-6049(01)00110-6[Crossref]
• [6] M. Chroma, J. Pinkas, I. Pakutinskiene, A. Beganskiene, A. Kareiva, Ceram. Int. 31, 1123 (2005) http://dx.doi.org/10.1016/j.ceramint.2004.11.012[Crossref]
• [7] M. Retuerto, J.A. Alonso, M.J. Martinez-Lope, N. Menedez, J. Tornero, M. Garcia-Hernandez, J. Mater. Chem. 16, 865 (2006) http://dx.doi.org/10.1039/b512951f[Crossref]
• [8] J. Zylberberg, Z.-G. Ye, J. Appl. Phys. 100, 086102 (2006) http://dx.doi.org/10.1063/1.2358827[Crossref]
• [9] G. Thornton, B.C. Tofield, A.W. Hewat, J. Solid State Chem. 61, 301 (1986) http://dx.doi.org/10.1016/0022-4596(86)90035-6[Crossref]
• [10] J.C. Walmsley, A. Bardal, K. Kleveland, M.-A. Einarsrud, T. Grande, J. Mater. Sci. 35, 4251 (2000) http://dx.doi.org/10.1023/A:1004867815051[Crossref]
• [11] J.A. Alonso, M.J. Martinez-Lope, C. de la Calle, V. Pomjakushin, J. Mater. Chem. 16, 1555 (2006) http://dx.doi.org/10.1039/b515607f[Crossref]
• [12] N.V. Minh, I.-S. Yang, Vibr. Spectrosc. 42, 353 (2006) http://dx.doi.org/10.1016/j.vibspec.2006.05.027[Crossref]
• [13] M. Cherry, M.S. Islam, C.R.A. Catlow, J. Solid State Chem. 118, 125 (1995) http://dx.doi.org/10.1006/jssc.1995.1320[Crossref]
• [14] C.H. Chen, H. Kruidhof, H.J.M. Bouwmeester, A.J. Burggraaf, J. Appl. Electrochem. 27, 71 (1997) http://dx.doi.org/10.1023/A:1026471016927[Crossref]
• [15] A.A. Yaremchenko, V.V. Kharton, A.P. Viskup, E.N. Naumovich, V.N. Tikhonovich, N.M. Lapchuk, Solid State Ionics 120, 65 (1999) http://dx.doi.org/10.1016/S0167-2738(98)00469-X[Crossref]
• [16] N. Orlovskaya, D. Ge, A. Nicholls, Key Eng. Mater. 206-213, 1321 (2002) http://dx.doi.org/10.4028/www.scientific.net/KEM.206-213.1321[Crossref]
• [17] B. Kucharczyk, W. Tylus, Catal. Today 90, 121 (2004) http://dx.doi.org/10.1016/j.cattod.2004.04.016[Crossref]
• [18] A. Kahoul, A. Hammouche, G. Poillerat, R.W. De Doncker, Catal. Today 89, 287 (2004) http://dx.doi.org/10.1016/j.cattod.2003.12.003[Crossref]
• [19] A. Patil, S. Dash, S.C. Parida, V. Venugopal, J. All. Comp. 384, 274 (2004) http://dx.doi.org/10.1016/j.jallcom.2004.04.090[Crossref]
• [20] Z.Q. Deng, W. Liu, C.S. Chen, H. Lu, W.S. Yang, Solid State Ionics 170, 187 (2004) http://dx.doi.org/10.1016/j.ssi.2004.04.006[Crossref]
• [21] G.W. Chadzynski, D. Sternik, P. Staszczuk, B. Kucharczyk, J. Therm. Anal. Calorim. 78, 441 (2004) http://dx.doi.org/10.1023/B:JTAN.0000046109.22907.54[Crossref]
• [22] A. Weidenkaff, R. Robert, M. Aguirre, L. Bocher, T. Lippert, S. Canulescu, Renewable Energy 33, 342 (2008) http://dx.doi.org/10.1016/j.renene.2007.05.032[Crossref]
• [23] J.L. Routbort, R. Doshi, M. Krumpelt, Solid State Ionics 90, 21 (1996) http://dx.doi.org/10.1016/S0167-2738(96)00402-X[Crossref]
• [24] H.Y. Tu, Y. Takeda, N. Imanishi, O. Yamamoto, Solid State Ionics 100, 283 (1997) http://dx.doi.org/10.1016/S0167-2738(97)00360-3[Crossref]
• [25] S.B. Adler, Solid State Ionics 111, 111 (1998) http://dx.doi.org/10.1016/S0167-2738(98)00179-9[Crossref]
• [26] R.H.E. van Doorn, A.J. Burggraaf, Solid State Ionics 128, 65 (2000) http://dx.doi.org/10.1016/S0167-2738(99)00282-9[Crossref]
• [27] S.J. Skinner, Int. J. Inorg. Mater. 3, 113 (2001) http://dx.doi.org/10.1016/S1466-6049(01)00004-6[Crossref]
• [28] V.G. Prokhorov, Y.P. Lee, K.W. Kim, G.G. Kaminsky, V.M. Ishchuk, I.N. Chukanova, Mater. Sci. Forum 373-376, 605 (2001)
• [29] G.S. Wang, X.J. Meng, Z.Q. Lai, J. Yu, J.L. Sun, J.G. Cheng, J. Tang, S.L. Guo, J.H. Chu, Appl. Phys. A 73, 1 (2001)
• [30] A.V. Kovalevsky, V.V. Kharton, V.N. Tikhonovich, E.N. Naumovich, A.A. Tonoyan, O.P. Reut, L.S. Boginsky, Mater. Sci. Eng. B 52, 105 (1998) http://dx.doi.org/10.1016/S0921-5107(97)00292-4[Crossref]
• [31] V.V. Kharton, A.A. Yaremchenko, A.V. Kovalevsky, A.P. Viskup, E.N. Naumovich, P.F. Kerko, J. Membr. Sci. 163, 307 (1999) http://dx.doi.org/10.1016/S0376-7388(99)00172-6[Crossref]
• [32] M. Sogaard, P.V. Hendriksen, M. Mogensen, F.W. Poulsen, E. Skou, Solid State Ionics 177, 3285 (2006) http://dx.doi.org/10.1016/j.ssi.2006.09.005[Crossref]
• [33] K. Asai, O. Yokokura, N. Nishimori, H. Chou, J.M. Tranquada, G. Shirane, S. Higuchi, Y. Okajima, K. Kohn, Phys. Rev. B 50, 3025 (1994) http://dx.doi.org/10.1103/PhysRevB.50.3025[Crossref]
• [34] M.A. Senaris-Rodriguez, J.B. Goodenough, J. Solid State Chem. 118, 323 (1995) http://dx.doi.org/10.1006/jssc.1995.1351[Crossref]
• [35] S. Mukherjee, R. Ranganathan, P.S. Anikumar, P.A. Joy, Phys. Rev. B 54, 9367 (1996) http://dx.doi.org/10.1103/PhysRevB.54.9267[Crossref]
• [36] P.S. Anil Kumar, P.A. Joy, S.K. Date, J. Phys.: Condens. Matter 10, L487 (1998) http://dx.doi.org/10.1088/0953-8984/10/29/001[Crossref]
• [37] D.N.H. Nam, K. Jonason, P. Nordblad, N.V. Khiem, N.X. Phuc, Phys. Rev. B 59, 4189 (1998) http://dx.doi.org/10.1103/PhysRevB.59.4189[Crossref]
• [38] R. Caciuffo, D. Rinaldi, G. Barucca, J. Mira, J. Rivas, M.A. Senaris-Rodriguez, P.G. Radaelli, D. Fiorani, J.B. Goodenough, Phys. Rev. B 59, 1068 (1999) http://dx.doi.org/10.1103/PhysRevB.59.1068[Crossref]
• [39] J. Mira, J. Rivas, M. Vazquez, J.M. Garcia-Beneytez, J. Arcas, R.D. Sanchez, M.A. Senaris-Rodriguez, Phys. Rev. B 59, 123 (1999) http://dx.doi.org/10.1103/PhysRevB.59.123[Crossref]
• [40] R. Ganguly, I.K. Gopalakrishnan, J.V. Yakhmi, Physica B 271, 116 (1999) http://dx.doi.org/10.1016/S0921-4526(99)00245-8[Crossref]
• [41] S. Chaudhary, S.B. Roy, P. Chaddah, J. All. Comp. 326, 112 (2001) http://dx.doi.org/10.1016/S0925-8388(01)01236-1[Crossref]
• [42] M. James, D. Cassidy, D.J. Goossens, R.L. Withers, J. Solid State Chem. 177, 1886 (2004) http://dx.doi.org/10.1016/j.jssc.2004.01.012[Crossref]
• [43] J. Livage, M. Henry, C. Sanchez, J. Solid State Chem. 18, 259 (1988) http://dx.doi.org/10.1016/0079-6786(88)90005-2[Crossref]
• [44] C.J. Brinker, G.W. Scherrer, Sol-gel science: the physics and chemistry of sol-gel processing, Academic Press, New York, 1990
• [45] C. Sanchez, G.J.D.A.A. Soler-Illia, F. Ribot, D. Grosso, J. C. R. Chimie 6, 1131 (2003) [Crossref]
• [46] B.L. Cushing, V.L. Kolesnichenko, C.J. O`Connor, Chem. Rev. 104, 3893 (2004) http://dx.doi.org/10.1021/cr030027b[Crossref]
• [47] J.D. Mackenzie, E.P. Bescher, Acc. Chem. Res. 40, 810 (2007) http://dx.doi.org/10.1021/ar7000149[Crossref]
• [48] T. Ishigaki, S. Yamauchi, K. Kishio, J. Mizusaki, K. Fueki, J. Solid State Chem. 73, 179 (1988) http://dx.doi.org/10.1016/0022-4596(88)90067-9[Crossref]
• [49] Z.L. Wang, J. Zhang, Phil. Mag. A 72, 1513 (1995) http://dx.doi.org/10.1080/01418619508243928[Crossref]
• [50] A. Wold, R. Ward, Notes 30, 1029 (1954)
• [51] M. Matsuda, K. Ihara, M. Miyake, Solid State Ionics 172, 57 (2004) http://dx.doi.org/10.1016/j.ssi.2004.02.030[Crossref]
• [52] F.J. Berry, J.R. Gancedo, J.F. Marco, X. Ren, J. Solid State Chem. 177, 2101 (2004) http://dx.doi.org/10.1016/j.jssc.2004.02.019[Crossref]
• [53] A.N. Jain, S.K. Tiwari, R.N. Singh, P. Chartier, J. Chem. Soc.-Faraday Transac. 91, 1871 (1995) http://dx.doi.org/10.1039/ft9959101871[Crossref]
• [54] T. Vaz, A.V. Salker, Mater. Sci. Eng. B 143, 81 (2007) http://dx.doi.org/10.1016/j.mseb.2007.07.027[Crossref]
• [55] S. Faaland, T. Grande, M.-A. Einarsrud, P.E. Vullum, R. Holmestad, J. Am. Ceram. Soc. 88, 726 (2005) http://dx.doi.org/10.1111/j.1551-2916.2005.00165.x[Crossref]
• [56] M. Wallin, N. Cruise, U. Klement, A. Palmqvist, M. Skoglundh, Coll. Surf. A: Physicochem. Eng. Aspects 238, 27 (2004) http://dx.doi.org/10.1016/j.colsurfa.2004.02.019[Crossref]
• [57] W. Chen, F. Li, J. Yu, Mater. Lett. 61, 397 (2007) http://dx.doi.org/10.1016/j.matlet.2006.04.069[Crossref]
• [58] A. Baykal, N. Kasapoglu, Y. Koseoglu, A.C. Basarab, H. Kavas, M.S. Toprak, Cent. Eur. J. Chem. 6, 125 (2008) http://dx.doi.org/10.2478/s11532-007-0070-4[Crossref]
• [59] L. Huang, M. Bassir, S. Kaliaguine, Mater. Chem. Phys. 101, 259 (2007) http://dx.doi.org/10.1016/j.matchemphys.2006.08.008[Crossref]
• [60] N. Orlovskaya, K. Kleveland, T. Grande, M.-A. Einarsrud, J. Eur. Ceram. Soc. 20, 51 (2000) http://dx.doi.org/10.1016/S0955-2219(99)00084-9[Crossref]
• [61] C.R. Dyck, Z.B. Yu, V.D. Krstic, Solid State Ionics 171, 17 (2004) http://dx.doi.org/10.1016/j.ssi.2004.02.014[Crossref]
• [62] E. Garskaite, K. Gibson, A. Leleckaite, J. Glaser, D. Niznansky, A. Kareiva, H.-J. Meyer, Chem. Phys. 323, 204 (2006) http://dx.doi.org/10.1016/j.chemphys.2005.08.055[Crossref]
• [63] A. Zalga, A. Beganskiene, A. Kareiva, Polish J. Chem. 81, 1547 (2007)
• [64] A. Katelnikovas, J. Barkauskas, F. Ivanauskas, A. Beganskiene, A. Kareiva, J. Sol-Gel Sci. Techn. 41, 193 (2007) http://dx.doi.org/10.1007/s10971-006-9002-6[Crossref]
• [65] S. Cizauskaite, V. Reichlova, G. Nenartaviciene, A. Beganskiene, J. Pinkas, A. Kareiva, Mater. Chem. Phys. 102, 105 (2007) http://dx.doi.org/10.1016/j.matchemphys.2006.11.016[Crossref]
• [66] A. Katelnikovas, T. Justel, D. Uhlich, J.-E. Jorgensen, S. Sakirzanovas, A. Kareiva, Chem. Eng. Comm. 195, 758 (2008) http://dx.doi.org/10.1080/00986440701691194[Crossref]
• [67] A. Katelnikovas, A. Kareiva, Mater. Lett. 62, 1655 (2008) http://dx.doi.org/10.1016/j.matlet.2007.09.053[Crossref]
• [68] K. Nakanishi, Infrared Absorption Spectroscopy (Holden Day, San Francisco, (1977)
• [69] K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (John Wiley and Sons, New York, 1986)
• [70] B. Schrader, Infrared and Raman Spectroscopy. Methods and Applications (VCH, Weinheim, 1995)
• [71] S. Cizauskaite, V. Reichlova, G. Nenartaviciene, A. Beganskiene, J. Pinkas, A. Kareiva, Mater. Sci.-Poland 25, 755 (2007)

Identifiers

DOI

10.2478/s11532-008-0045-0