Palladium(0)-catalyzed amination of allylic natural terpenic functionalized olefins

• Authors: Soufiane Houssame , Hafid Anane , Larbi Firdoussi , Abdellah Karim
• Languages of publication: EN

Abstracts

EN

The palladium(0) catalyzed amination of allylic acetates and carbonates derivatives from terpenic olefins was carried out under mild conditions. The reaction offers a very good method for the preparation of allylic amines and thus to provide a useful entry to new functionalized terpenic olefin products. The mechanism involving a formation of p-allyl-palladium intermediate complex is in good agreement with the results obtained with the optically active substrates, as well as via an analysis of the observed regio-and stereoselectivity. [...]

Keywords

EN

Palladium; Allylic amination; Allylic functionalized terpenic olefin

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2008
• Volume: 6
• Issue: 3
• Pages: 470-476

Dates

published

1 - 9 - 2008

online

11 - 8 - 2008

Contributors

author

Soufiane Houssame

• Laboratoire de Chimie de Coordination, Faculté des Sciences-Semlalia, Université Cadi Ayyad, BP 2390, Marrakech, Morocco

author

Hafid Anane

• Département Sciences de la matière, Faculté Polydisciplinaire de Safi, Route Sidi bouzid, B.P 4162, Safi Université Cadi Ayyad, Morocco

author

Larbi Firdoussi

• Laboratoire de Chimie de Coordination, Faculté des Sciences-Semlalia, Université Cadi Ayyad, BP 2390, Marrakech, Morocco

author

Abdellah Karim

• Laboratoire de Chimie de Coordination, Faculté des Sciences-Semlalia, Université Cadi Ayyad, BP 2390, Marrakech, Morocco

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Identifiers

DOI

10.2478/s11532-008-0042-3