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Journal

2008 | 6 | 2 | 237-244

Article title

Kinetics and mechanism of the C-S coupling reactions of aryl Grignard reagents with aryl arenesulfonates

Content

Title variants

Languages of publication

EN

Abstracts

EN
The kinetics of the C-S coupling of arylmagnesium bromides with phenyl tosylate has been studied in THF: toluene at 90°C. The reaction is first order in Grignard reagent and first order in phenyl tosylate. Kinetic data, Hammett relationship and activation parameters are consistent with a nucleophilic addition mechanism involving rate determining attack of carbanion to sulfonyl group followed by a fast phenoxide group leaving. [...]

Publisher

Journal

Year

Volume

6

Issue

2

Pages

237-244

Physical description

Dates

published
1 - 6 - 2008
online
17 - 4 - 2008

Contributors

author
  • Ankara University, Science Faculty, Beşevler, Ankara, 06100, Turkey
author
  • Ankara University, Science Faculty, Beşevler, Ankara, 06100, Turkey

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-008-0017-4
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