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Number of results

Journal

2008 | 6 | 1 | 115-124

Article title

Investigation on the catalytic activity of doped low-percentage oxide catalysts Mn/ZnO obtained from oxalate precursor

Content

Title variants

Languages of publication

EN

Abstracts

EN
The precursors with a low manganese content ≤ 0.07% Mn were synthesized by spontaneous crystallization from Zn2+, Mn2+ and C2O42−-containing solutions. The initial ratio Zn2+:C2O42− = 1:1 and 1:2 influences the morphology and prevailing orientations of the crystallites in the oxalate samples. The presence of such small Mn content in the samples does not change the morphology or size of the crystals. The ZnO and Mn/ZnO oxides with manganese content from 0.51×10−2 to 15.1×10−2 Wt % are obtained after thermal decomposition of the oxalates. The oxides preserved the morphology of the precursors. The catalytic tests show that the pure ZnO has a poor activity for CO oxidation reaction. Its doping with Mn promotes the catalytic activity (up from twice to five times) in spite of the very low contents of the dopants. The observed increase of the activity depends on both dopant concentration and Zn2+:C2O42− ratio, probably due to the different mechanism of the manganese inclusion and different morphology of the oxides. The catalysts of the 1:2 series are more active in CO oxidation reaction. [...]

Keywords

Publisher

Journal

Year

Volume

6

Issue

1

Pages

115-124

Physical description

Dates

published
1 - 3 - 2008
online
1 - 3 - 2008

Contributors

  • Department of Inorganic Chemistry, Faculty of Chemistry, University of Sofia, 1 J. Bouchier Av., Sofia, 1164, Bulgaria
  • Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., bl 11, Sofia, 1113, Bulgaria
  • Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., bl 11, Sofia, 1113, Bulgaria

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-007-0071-3
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