Separation of Ga(III) from Cu(II), Ni(II) and Zn(II) in aqueous solution using synthetic polymeric resins

• Authors: A. Massaoud , H. Hanafi , T. Siyam , Z. Saleh , F. Ali
• Languages of publication: EN

Abstracts

EN

Poly (acrylamide-acrylic acid-dimethylaminoethylmethacrylate), p(AM-AA-DMAEM) and Poly(acrylamide-acrylic acid)-ethylenediaminetetracetic acid disodium, p(AM-AA)-EDTANa2 were prepared by gamma radiation-induced template polymerization technique and used for the separation of Ga (III) from Cu (II), Ni (II), and Zn (II) in aqueous media. The effect of pH and contact time on the separation process was studied. The optimum pH value for the separation process is 3–3.5. The result shows that Ga (III) is first extracted while Cu (II), Ni (II) and Zn(II) are slightly extracted at this pH value. The recovery of metals using HCl, HNO3 and H2SO4 has been studied. The resins may be regenerated using 2M HCl solutions. [...]

Keywords

EN

Separation of Gallium (III) from Zinc (II); Copper (II) and Nickel (II); Polymeric resins

• Journal: Open Chemistry
• Year: 2008
• Volume: 6
• Issue: 1
• Pages: 39-45

Dates

published

1 - 3 - 2008

online

1 - 3 - 2008

Contributors

author

A. Massaoud

• Cyclotron project, Nuclear Research Centre, Atomic Energy Authority, Cairo, Egypt,

author

H. Hanafi

• Cyclotron project, Nuclear Research Centre, Atomic Energy Authority, Cairo, Egypt

author

T. Siyam

• Nuclear Chemistry Department, Hot lab. Center, Atomic Energy Authority, Cairo, Egypt

author

Z. Saleh

• Cyclotron project, Nuclear Research Centre, Atomic Energy Authority, Cairo, Egypt

author

F. Ali

• Chemistry Department, Faculty of Science, Menofia University, Menofia, Egypt

References

• [1] R.A. Beauvais, S.D. Alexandratos, React. Funct. Polym. 36, 113, (1998) http://dx.doi.org/10.1016/S1381-5148(98)00016-9[Crossref]
• [2] A. Warshawsky, In: D.C. Sherrington, P. Hodge (Eds.), Syntheses and Separations Using Functional Polymers, (Wiley, New York, 1988)
• [3] A.W. Trochimczuk, S. Czerwinska, React. Funct. Polym. 63, 215 (2005) http://dx.doi.org/10.1016/j.reactfunctpolym.2005.03.002[Crossref]
• [4] S.K. Sahni, J. Reedijk, Coord. Chem. Rev. 59, 1 (1984) http://dx.doi.org/10.1016/0010-8545(84)85053-5[Crossref]
• [5] W.W. Schulz, J.D. Navratil, Sep. Sci. Technol. 19, 927, (1984) http://dx.doi.org/10.1080/01496398408068601[Crossref]
• [6] T. Hayashita, K. Yamasaki, J.C. White, S.P. Kasprzyk, R.A. Bartsch, Sep. Sci. Technol. 31, 2195 (1996) http://dx.doi.org/10.1080/01496399608001040[Crossref]
• [7] B. Petkof, In: Mineral Facts and Problems, (U.S. Department of the Interior, Bureau of Mines, Bulletin 675, 1985)
• [8] I. Mihaylov, P.A. Distin, Can. Metall. Quart. 32(1), 21, (1993) [Crossref]
• [9] M.L. Thakur, Int. J. Appl. Radiat. Is. 28, 183 (1977) http://dx.doi.org/10.1016/0020-708X(77)90172-7[Crossref]
• [10] B.P.C. Gutierrez, J. Caca, J. Chem. Technol. Biot. 61, 241 (1994) http://dx.doi.org/10.1002/jctb.280610310[Crossref]
• [11] I. Mohaylov, P.A. Distin, Hydrometallurgy 37, 221 (1995) http://dx.doi.org/10.1016/0304-386X(94)00045-5[Crossref]
• [12] M.K. Das, N. Ramamoorthy, Indian J. Nucl. Med., 10, 63 (1995)
• [13] M.S. Gidwani, S. K. Menon, Y.K. Agrawal, React. Funct. Polym 53, 143 (2002) http://dx.doi.org/10.1016/S1381-5148(02)00169-4[Crossref]
• [14] J.S. Liu., H. Chen, X.Y. Chen, Z.L. Guo, Y.C. Hu, C.P. Liu, Y.Z. Sun, Hydrometallurgy 82, 137 (2006) http://dx.doi.org/10.1016/j.hydromet.2006.03.008[Crossref]
• [15] S. Chegrouche, A. Bensmaili, Water Res. 36, 2898 (2002) http://dx.doi.org/10.1016/S0043-1354(01)00498-5[Crossref]
• [16] T. Siyam, Des. Monomers Polym. 4, 107 (2001) http://dx.doi.org/10.1163/156855500300203377[Crossref]
• [17] T. Siyam, H. M. Abdel-Aziz and F. H. El-Sweify, Current Trend in Polymer Science 7, 157 (2002)
• [18] T. Siyam and R. Ayoub, J. Macromol. Sci. Pure 34, 1727 (1997) http://dx.doi.org/10.1080/10601329708010038[Crossref]
• [19] T. Siyam, In: Chermisinof, (Ed.). Handbook of Engineering Polymeric Materials (Dekker, New York, 1997) 119
• [20] A.A. El-Zahhar, H. M. Addel-Aziz, and T. Siyam, J. Macromol. Sci. Pure 44, 215 (2007) http://dx.doi.org/10.1080/10601320601031382[Crossref]
• [21] A.A. El-Zahhar, Sanaa. R. Mahdy and T. Siyam, 8th Intern. Conf. on Nucl. Sci.& Appls. 7–12 Feb. Cairo, Egypt (8th International Conference on Nuclear Science & Applications 2004) 325

Identifiers

DOI

10.2478/s11532-007-0054-4