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Journal
2007 | 5 | 2 | 546-556
Article title

Synthesis and proton conductivity of anhydrous dendritic electrolytes

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EN
Abstracts
EN
Water soluble PEG cored dendritic hexa-acid which comprises peripheral carboxylic acidic groups were prepared via nucleophilic substitution reactions. Novel anhydrous proton conducting electrolytes were prepared by incorporation of the heterocyclic protogenic solvent imidazole (Im) into PEG cored dendritic hexa acid, (PEG-HA), at several molar ratios of Im to-COOH units of PEG-HA. The complexation of PEG-HA and Im was illustrated by infrared spectroscopy (FT-IR). The materials are thermally stable up to 150 °C as evidenced by thermogravimetry analysis (TGA). Differential scanning calorimetry (DSC) results verified that the organic electrolytes are homogeneous and amorphous. The proton conductivities were characterized by means of AC impedance spectroscopy and a maximum conductivity of 1 × 10−3 S/cm was measured at 120 °C in the anhydrous state. [...]
Publisher

Journal
Year
Volume
5
Issue
2
Pages
546-556
Physical description
Dates
published
1 - 6 - 2007
online
27 - 2 - 2007
Contributors
author
  • Department of Chemistry, Fatih University, 34500, Buyukcekmece, Istanbul, Turkey
author
  • Department of Chemistry, Fatih University, 34500, Buyukcekmece, Istanbul, Turkey, metin@fatih.edu.tr
author
  • Department of Chemistry, Fatih University, 34500, Buyukcekmece, Istanbul, Turkey, bozkurt@fatih.edu.tr
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-007-0016-x
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