A new oxidation process. Transformation of gem-bishydroperoxides into esters

• Authors: Alexander Terent’ev , Maxim Platonov , Alexander Kutkin
• Languages of publication: EN

Abstracts

EN

A new oxidation process has been found where α,ω-dicarboxylic acid esters and ω-hydroxycarboxylic acid esters are formed on heating gem-bishydroperoxides in alcohol in the presence of BF3·Et2O. By addition of H2O2 to this reaction α,ω-dicarboxylic acid esters are formed almost selectively.

Keywords

EN

Oxidation; gem-bishydroperoxides ; α,ω-diearboxylic acid esters; ω-hydroxycarboxylic acid esters; hydrogen peroxide; boron trifluoride

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2006
• Volume: 4
• Issue: 2
• Pages: 207-215

Dates

published

1 - 6 - 2006

online

1 - 6 - 2006

Contributors

author

Alexander Terent’ev

• N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Leninsky Prospect 47, Moscow, Russia

author

Maxim Platonov

• N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Leninsky Prospect 47, Moscow, Russia

author

Alexander Kutkin

• N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Leninsky Prospect 47, Moscow, Russia

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Identifiers

DOI

10.2478/s11532-006-0012-6